Ammonium chromate

Ammonium chromate
Names
Other names
Ammonium chromate(IV)
Identifiers
CAS Number
  • 7788-98-9
3D model (JSmol)
  • Interactive image
ChemSpider
  • 22997
ECHA InfoCard 100.029.217 Edit this at Wikidata
EC Number
  • 232-138-4
PubChem CID
  • 24595
UNII
  • X7I33TTT6D
UN number 3085,3077
CompTox Dashboard (EPA)
  • DTXSID3064857 Edit this at Wikidata
InChI
  • InChI=1S/Cr.2H3N.4O/h;2*1H3;;;;/q;;;;;2*-1/p+2
    Key: MFFLHUNPSHBKRG-UHFFFAOYSA-P
  • [NH4+].[NH4+].[O-][Cr](=O)(=O)[O-]
Properties
Chemical formula
(NH4)2CrO4
Molar mass 152.07 g/mol
Appearance yellow crystals
Density 1.90 g/ml
Melting point 185 °C (365 °F; 458 K) decomposes[1]
Solubility in water
24.8 g/100ml (0 °C)
37.36 g/100ml (25 °C)[1]
45.3 g/100ml (40 °C)
70.06 g/100ml (75 °C)[1][2]
Thermochemistry
Std molar
entropy (S298)
657 J/K·mol
Std enthalpy of
formation fH298)
-1163 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic
GHS labelling:
Pictograms
GHS03: OxidizingGHS05: CorrosiveGHS08: Health hazardGHS09: Environmental hazard[3]
Danger
Hazard statements
H272, H314, H317, H334, H350, H400[3]
Precautionary statements
P201, P220, P261, P273, P280, P305+P351+P338[3]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Ammonium chromate is a salt with the formula (NH4)2CrO4. It forms yellow, monoclinic crystals; made from ammonium hydroxide and ammonium dichromate; used in photography as a sensitizer for gelatin coatings. It is often used in photography, textile printing, and fixing chromate dyes on wool. It is also used as an analytical reagent, catalyst, and corrosion inhibitor. It is soluble in water, and, when applied, can cause irritation in the mucous membrane, eyes, respiratory tract, skin, etc. It may cause skin sensitization after prolonged contact. It is also known to be carcinogenic (cancer-causing), and it can cause tissue ulceration and injury to the liver and kidneys.[4]

See also

References

  1. ^ a b c Perry, Dale L. (2011). Handbook of Inorganic Compounds, Second Edition. Boca Raton, Florida: CRC Press. ISBN 978-1-43981462-8. Retrieved 2014-04-28.
  2. ^ "Ammonium chromate".
  3. ^ a b c Sigma-Aldrich Co., Ammonium chromate. Retrieved on 28-04-2014.
  4. ^ Information preview for Ammonium chromate, GIDEON
  • v
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Ammonium salts
Inorganic salts
monatomic anions
  • NH4F
  • (NH4)2S
  • NH4Cl
  • (NH4)2Se
  • NH4Br
  • NH4I
oxyanions
  • NH4NO2
  • NH4NO3
  • (NH4)2CO3
  • (NH4)4UO2(CO3)2
  • (NH4)HCO3
  • NH4OCN
  • (NH4)3PO4
  • (NH4)2HPO4
  • (NH4)H2PO4
  • (NH4PO4)n(OH)2
  • NH4NaHPO4
  • (NH4)2SO3
  • (NH4)2SO4
  • (NH4)Al(SO4)2·12H2O
  • (NH4)2Fe(SO4)2·6H2O
  • NH4Fe(SO4)2·12H2O
  • NH4SO3NH2
  • (NH4)HSO4
  • (NH4)2S2O8
  • (NH4)2S2O3
  • NH4ClO3
  • NH4ClO4
  • NH4VO3
  • (NH4)2CrO4
  • (NH4)2Cr2O7
  • NH4MnO4
  • (NH4)3AsO4
  • (NH4)2MoO4
  • (NH4)6Mo7O24
  • (NH4)3Mo12PO40
  • NH4IO3
  • (NH4)2Ce(NO3)6
  • (NH4)8Ce2(SO4)8·4H2O
  • (NH4)10H2W12O42·4H2O
  • NH4ReO4
other anions
  • NH4BF4
  • NH4N3
  • NH4CN
  • (NH4)HF2
  • (NH4)3AlF6
  • (NH4)SiF6
  • (NH4)HS
  • NH4SCN
  • (NH4)2ZnCl4
  • (NH4)2MoS4
  • NH4I3
  • (NH4)2TeCl6
  • (NH4)2IrCl6
  • (NH4)2PtCl6
Organic salts
  • v
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  • e
Chromates
  • Na2CrO4
  • K2CrO4
  • Cs2CrO4
  • BeCrO4
  • MgCrO4
  • CaCrO4
  • SrCrO4
  • BaCrO4
  • Fe2(CrO4)3
  • NiCrO4
  • Ag2CrO4
  • ZnCrO4
  • CdCrO4
  • PbCrO4
  • Pb2CrO5
  • [NH4]2CrO4
Chlorochromates
  • KCrO3Cl
  • [C5H5NH]CrO3Cl
Chromate esters
  • CrO2(OC(CH3)3)2
  • CrO2(OSi(OCH3)3)2
Dichromates
  • Na2Cr2O7
  • K2Cr2O7
  • Ag2Cr2O7
  • [NH4]2Cr2O7
  • [C5H5NH]2Cr2O7
Related
  • H2CrO4/H2Cr2O7
  • EuCrO4
  • CrO5