Arsenide bromide

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

List

formula system space group unit cell Å volume density comment ref
(Ca2−x□x)(As1−xBr1+x) Ca2AsBr cubic a=6.05 3.47 yellow, or dark brown [1][2]
Ca3AsBr3 cubic Pm3 a=5.91 3.48 colourless or yellow [1][2]
Cu6AsS5Br cubic F43m a=9.8763 4.80 [3][4]
(Ge38As8)+8⋅8 I− cubic Pm3n a=10.625 5.71 semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey [5]
I8As21Ge25 cubic Pm3n a=10.5963 Z=1 1189.77 6.143 colourless [6]
Cd2As3Br monoclinic C2/c a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4 5.76 black [7][8]
Cd4As2Br3 cubic Pa3 a=12.61 5.51 semiconductor band gap 1.8 eV [9]
Cd4PAsBr3 cubic Pa3 a=12.521 5.38 [10][4]
Cd4As2I1.5Br1.5 cubic Pa3 a=12.83 [11][4]
La3AsBr3 cubic I4132 a=12.09 5.50 [12]
Pr3AsBr3 cubic I4132 a=12.02 5.64 [12]
Hg2As3Br monoclinic C2/c a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4 7.79 black [7]
Hg4As2Br3 cubic Pa3 a=12.610 Z=8 2012.4 5.54 7.90 red; dark grey [13][14]
Hg19As10Br18 triclinic P1 a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078° 1314.3 dark brown [15]
(HgBr2)3(As4S4)2 monoclinic P21/c a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2 1399 [16]
Hg3AsS4Br hexagonal P63mc a = 7.430, c = 9.364 Z=2 [17]
(Hg6As4)[TiBr6]Br cubic Pa3 a= 1230.9 [18]
[Hg6As4](CrBr6)Br cubic Pa a=12.275 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](FeBr6)Hg0.6 cubic Pa a=12.332 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](CuBr3)2 monoclinic I2/a a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6 dark red [20]
[Hg11As4](GaBr4)4 monoclinic C2/m [21]
Hg3AsSe4Br hexagonal P63mc a = 7.707, c = 9.47 Z=2 [17]
(Hg2Cd2As2Br)Br orthorhombic Pmma a = 8.791, b = 4.701, c = 9.779, Z=2 404.2 7.688 dark red [22]
(Hg6As4)(CdBr6) cubic Pa3 a=12.3738 Z=4 1894.6 7.345 red; air stable; band gap 1.94 [23]
[Hg6As4][InBr6]Br cubic Pa3 a=12.3511 Z=4 1884.2 dark red [24]
[Hg4As2](InBr3.5As0.5) Hexagonal P63/mmc a = 7.7408, c = 12.535, Z=2 650.47 [25]
[Hg6As4Br3](SnBr3) cubic P213 a=12.383 Z=4 [26]
[Hg6As4][YbBr6]Br cubic Pa3 a=12.362 Z=4 1889.1 7.860 dark red [27]
Hg9As4Bi2Br12 tetragonal P43 a=10.865 b=10.865 c=28.357 Z=4 3347.5 6.91 orange [28]

References

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  20. ^ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework". Journal of Cluster Science. 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. S2CID 95453360.
  21. ^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
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  28. ^ Puff, H.; Grönke, M.; Kilger, B.; Möltgen, P. (November 1984). "Darstellung und Struktur des Mercuroarsoniumbromo-bismutats [Hg7(HgBr)2As4] [Bi2Br10]". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 120–128. doi:10.1002/zaac.19845181112. ISSN 0044-2313.
  • v
  • t
  • e
Arsenides
Binary arsenides
AsH3
+H 		He
LiAs Be BAs C +N +O F Ne
Na3As Mg AlAs -Si P S +Cl Ar
K CaAs Sc Ti V Cr MnAs Fe CoAs Ni Cu Zn3As2 GaAs -Ge As Se +Br Kr
Rb Sr YAs Zr Nb MoAs2 Tc Ru Rh PdAs2 Ag Cd3As2 InAs -Sn Sb +Te +I Xe
Cs Ba * Lu Hf TaAs WAs2 Re Os Ir Pt Au Hg Tl Pb BiAs Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* La Ce PrAs Nd Pm SmAs Eu Gd Tb Dy Ho Er Tm Yb
** Ac Th Pa U NpAs
NpAs2 		PuAs Am Cm Bk Cf Es Fm Md No
Ternary arsenidesQuaternary arsenidesQuinary arsenidesSee also
  • v
  • t
  • e
Salts and covalent derivatives of the bromide ion
HBr He
LiBr BeBr2 BBr3
+BO3 		CBr4
+C 		NBr3
BrN3
NH4Br
NOBr
+N 		Br2O
BrO2
Br2O3
Br2O5 		BrF
BrF3
BrF5 		Ne
NaBr MgBr2 AlBr
AlBr3 		SiBr4 PBr3
PBr5
PBr7
+P 		S2Br2
SBr2 		BrCl Ar
KBr CaBr2
 ScBr3 TiBr2
TiBr3
TiBr4 		VBr2
VBr3 		CrBr2
CrBr3 		MnBr2 FeBr2
FeBr3 		CoBr2 NiBr2
NiBr42− 		CuBr
CuBr2 		ZnBr2 GaBr3 GeBr2
GeBr4 		AsBr3
+As
+AsO3 		SeBr2
SeBr4 		Br2 Kr
RbBr SrBr2 YBr3 ZrBr3
ZrBr4 		NbBr5 MoBr2
MoBr3
MoBr4 		TcBr4 RuBr3 RhBr3 PdBr2 AgBr CdBr2 InBr
InBr3 		SnBr2
SnBr4 		SbBr3
+Sb
-Sb 		Te2Br
TeBr4
+Te 		IBr
IBr3 		XeBr2
CsBr BaBr2 * LuBr3 HfBr4 TaBr5 WBr5
WBr6 		ReBr3 OsBr3
OsBr4 		IrBr3
IrBr
4 		PtBr2
PtBr4 		AuBr
AuBr3 		Hg2Br2
HgBr2 		TlBr PbBr2 BiBr3 PoBr2
PoBr4 		AtBr Rn
FrBr RaBr2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaBr3 CeBr3 PrBr3 NdBr2
NdBr3 		PmBr3 SmBr2
SmBr3 		EuBr2
EuBr3 		GdBr3 TbBr3 DyBr3 HoBr3 ErBr3 TmBr2
TmBr3 		YbBr2
YbBr3
** AcBr3 ThBr4 PaBr4
PaBr5 		UBr4
UBr5 		NpBr3
NpBr4 		PuBr3 AmBr2
AmBr3 		CmBr3 BkBr3 CfBr3 EsBr2
EsBr3 		Fm Md No