Bamberger triazine synthesis
The Bamberger triazine synthesis in organic chemistry is a classic organic synthesis of a triazine first reported by Eugen Bamberger in 1892.[1]
The reactants are an aryl diazonium salt obtained from reaction of the corresponding aniline with sodium nitrite and hydrochloric acid and the hydrazone of pyruvic acid. The azo intermediate converts to the benzotriazine in the third step with sulfuric acid in acetic acid.
See also
- From the same chemist: the Bamberger rearrangement
References
- ^ Hassner, A., Stumer, C., Organic Synthesis Based on Name Reactions: 2nd. Ed. Tetrahedron Organic Chemistry Series, Volume 22 Pergamon, Oxford ISBN 0-08-043260-3
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Topics in organic reactions
- Addition reaction
- Elimination reaction
- Polymerization
- Reagents
- Rearrangement reaction
- Redox reaction
- Regioselectivity
- Stereoselectivity
- Stereospecificity
- Substitution reaction
- A value
- Alpha effect
- Annulene
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- Antiaromaticity
- Aromatic ring current
- Aromaticity
- Baird's rule
- Baker–Nathan effect
- Baldwin's rules
- Bema Hapothle
- Beta-silicon effect
- Bicycloaromaticity
- Bredt's rule
- Bürgi–Dunitz angle
- Catalytic resonance theory
- Charge remote fragmentation
- Charge-transfer complex
- Clar's rule
- Conformational isomerism
- Conjugated system
- Conrotatory and disrotatory
- Curtin–Hammett principle
- Dynamic binding (chemistry)
- Edwards equation
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- Electron-rich
- Electron-withdrawing group
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- George S. Hammond
- Hammond's postulate
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- Hückel's rule
- Hyperconjugation
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- Kinetic isotope effect
- LFER solvent coefficients (data page)
- Marcus theory
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- Möbius–Hückel concept
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- Negative hyperconjugation
- Neighbouring group participation
- 2-Norbornyl cation
- Nucleophile
- Kennedy J. P. Orton
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- Phosphaethynolate
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- Taft equation
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- Walsh diagram
- Woodward–Hoffmann rules
- Woodward's rules
- Y-aromaticity
- Yukawa–Tsuno equation
- Zaitsev's rule
- Σ-bishomoaromaticity
