Fluocerite

Halite mineral
(repeating unit)(La,Ce)F3Strunz classification03.AC.15 (03)Dana classification09.03.04.02 (09)Crystal systemTrigonalCrystal classHexagonal scalenohedralSpace groupP3c1 (No. 165)Unit cell328.80 ų (Calculated from Unit Cell)IdentificationFormula mass196.02ColourGreenish-yellowCrystal habitPlaty, tabularCleavageIndistinct, ImperfectMohs scale hardness4-5LusterVitreousStreakWhiteDiaphaneityTransparent to translucentDensity5.93Birefringence0.006
Fluocerite-(Ce)
General
CategoryMineral
Formula
(repeating unit)
(La,Ce)F3
Strunz classification3/A.10-20
Dana classification9.3.4.1
Crystal systemTrigonal
Crystal classHexagonal Scalenohedral
Unit cell320.86 ų (Calculated from Unit Cell)
Identification
Formula mass196.99
ColourLight yellow; darkening to yellow- and red-brown; colourless to pale pink (transmitted light)
Crystal habitMassive, Primsatic
CleavageDistinct/Good
FractureIrregular/Uneven, Splintery, Sub-Conchoidal
TenacityBrittle
Mohs scale hardness4.5-5
LusterVitreous, Resinous, Pearly
StreakYellow-white
DiaphaneityTransparent to translucent
Specific gravity5.93 - 6.14
Density5.93 - 6.14 g/cm3 (Measured)
Birefringence0.005 - 0.007

Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula (Ce,La)F3.[1][2] The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system.[3]

Fluocerite-(Ce) was first described (without the Ce) in 1845 from hydrothermal veins in granite in Sweden.[4] Fluocerite-(La) was first described in 1969 from the type locality in central Kazakhstan.[3] The name tysonite was given in 1880 to the same type of mineral found in Colorado.[5][6] Tysonite-type structure is used for rare-earth fluorides with the P3c1 space group structure.[7]

References

  1. ^ "Fluocerite-(La) Mineral Data". webmineral.com. Retrieved 2021-02-12.
  2. ^ "Fluocerite-(Ce) Mineral Data". webmineral.com. Retrieved 2021-02-12.
  3. ^ a b "Fluocerite-(La)". www.mindat.org. Retrieved 2021-02-12.
  4. ^ "Fluocerite-(Ce)". www.mindat.org. Retrieved 2021-02-12.
  5. ^ Geijer, Per (1921-01-01). "On Fluocerite and Tysonite". Geologiska Föreningen i Stockholm Förhandlingar. 43 (1–2): 19–23. doi:10.1080/11035892109443886. ISSN 0016-786X.
  6. ^ Allen, Oscar D., and W. J. Comstock. "Bastnaesite and tysonite from Colorado." American Journal of Science 3.113 (1880): 390-393.
  7. ^ Dudney, Nancy J.; West, William C.; Nanda, Jagjit (2015-07-09). Handbook Of Solid State Batteries (Second ed.). World Scientific. ISBN 978-981-4651-91-2.
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HF He
LiF BeF2 BF
BF3
B2F4
CF4
CxFy
NF3
N2F4
OF
OF2
O2F2
O2F
F Ne
NaF MgF2 AlF
AlF3
SiF4 P2F4
PF3
PF5
S2F2
SF2
S2F4
SF4
S2F10
SF6
ClF
ClF3
ClF5
HArF
ArF2
KF CaF2 ScF3 TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
CrF6
MnF2
MnF3
MnF4
FeF2
FeF3
CoF2
CoF3
NiF2
NiF3
CuF
CuF2
ZnF2 GaF3 GeF4 AsF3
AsF5
SeF4
SeF6
BrF
BrF3
BrF5
KrF2
KrF4
KrF6
RbF SrF2 YF3 ZrF4 NbF4
NbF5
MoF4
MoF5
MoF6
TcF6 RuF3
RuF4
RuF5
RuF6
RhF3
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
PdF6
AgF
AgF2
AgF3
Ag2F
CdF2 InF3 SnF2
SnF4
SbF3
SbF5
TeF4
TeF6
IF
IF3
IF5
IF7
XeF2
XeF4
XeF6
XeF8
CsF BaF2 * LuF3 HfF4 TaF5 WF4
WF6
ReF6
ReF7
OsF4
OsF5
OsF6
OsF
7

OsF8
IrF3
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
AuF5·F2
HgF2
Hg2F2
HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF4
PoF6
At RnF2
RnF6
Fr RaF2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
* LaF3 CeF3
CeF4
PrF3
PrF4
NdF3 PmF3 SmF2
SmF3
EuF2
EuF3
GdF3 TbF3
TbF4
DyF3 HoF3 ErF3 TmF2
TmF3
YbF2
YbF3
** AcF3 ThF4 PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF3
AmF4
AmF6
CmF3 Bk Cf Es Fm Md No
PF6, AsF6, SbF6 compounds
  • AgPF6
  • KAsF6
  • LiAsF6
  • NaAsF6
  • HPF6
  • HSbF6
  • NH4PF6
  • KPF6
  • KSbF6
  • LiPF6
  • NaPF6
  • NaSbF6
  • TlPF6
AlF6 compounds
  • Cs2AlF5
  • K3AlF6
  • Na3AlF6
chlorides, bromides, iodides
and pseudohalogenidesSiF62-, GeF62- compounds
  • BaSiF6
  • BaGeF6
  • (NH4)2SiF6
  • Na2[SiF6]
  • K2[SiF6]
Oxyfluorides
  • BrOF3
  • BrO2F
  • BrO3F
  • LaOF
  • ThOF2
  • VOF
    3
  • TcO
    3
    F
  • WOF
    4
  • YOF
  • ClOF3
  • ClO2F3
Organofluorides
  • CBrF3
  • CBr2F2
  • CBr3F
  • CClF3
  • CCl2F2
  • CCl3F
  • CF2O
  • CF3I
  • CHF3
  • CH2F2
  • CH3F
  • C2Cl3F3
  • C2H3F
  • C6H5F
  • C7H5F3
  • C15F33N
  • C3H5F
  • C6H11F
with transition metal,
lanthanide, actinide, ammonium
  • VOF3
  • CrOF4
  • CrF2O2
  • NH4F
  • (NH4)2ZrF6
  • CsXeF7
  • Li2TiF6
  • Li2ZrF6
  • K2TiF6
  • Rb2TiF6
  • Na2TiF6
  • Na2ZrF6
  • K2NbF7
  • K2TaF7
  • K2ZrF6
  • UO2F2
nitric acids
bifluorides
  • KHF2
  • NaHF2
  • NH4HF2
thionyl, phosphoryl,
and iodosyl
  • F2OS
  • F3OP
  • PSF3
  • IOF3
  • IO3F
  • IOF5
  • IO2F
  • IO2F3

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