Gold chalcogenides

Class of chemical compound

Gold chalcogenides are compounds formed between gold and one of the chalcogens, elements from group 16 of the periodic table: oxygen, sulfur, selenium, or tellurium.

  • Gold(III) oxide, Au2O3. Decomposes into gold and oxygen above 160 °C, and dissolves in concentrated alkalis to form solutions which probably contain the [Au(OH)4] ion
  • Gold(I) sulfide, Au2S. Formed by reaction of hydrogen sulfide with gold(I) compounds.
  • Gold(III) sulfide, Au2S3, claimed material but unsubstantiated.
  • Gold tellurides: Au2Te3, Au3Te5, and AuTe2 (approximate formulæ) are known as non-stoichiometric compounds. They show metallic conductivity. Au3Te5 is a superconductor at 1.62 K.[1]

Gold telluride minerals, such as calaverite and krennerite (AuTe2), petzite (Ag3AuTe2), and sylvanite (AgAuTe2), are minor ores of gold (and tellurium). See telluride minerals for more information.

References

  1. ^ Luo, H.L.; Merriam, M.F.; Hamilton, D.C. (1964). "Superconducting Metastable Compounds". Science. 145 (3632): 581–583. Bibcode:1964Sci...145..581L. doi:10.1126/science.145.3632.581. PMID 17735806. S2CID 41529555.
  • Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  • v
  • t
  • e
Salts and covalent derivatives of the telluride ion
H2Te He
Li2Te BeTe B CTe2
(CH3)2Te
(NH4)2Te O F Ne
Na2Te MgTe Al2Te Si P0.8Te0.2 S Cl Ar
K2Te CaTe Sc2Te3 Ti VTe2 CrTe
Cr2Te3
MnTe
MnTe2
FeTe CoTe NiTe Cu2Te
CuTe
CuTe2
ZnTe GaTe
Ga2Te3
-Ga
GeTe
-Ge
As2Te3
As4Te3
+As
Se +Br Kr
Rb2Te SrTe Y2Te3 ZrTe5 NbTe2 MoTe2 Tc Ru Rh Pd Ag2Te CdTe In2Te3 SnTe
SnTe2
Sb2Te3 Te2-
Te2-
n
I Xe
Cs2Te BaTe * LuTe
Lu2Te3
HfTe5 TaTe2 WTe2
WTe3
ReTe2 Os Ir Pt AuxTey HgTe Tl2Te PbTe Bi2Te3 Po At Rn
Fr RaTe ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaTe
La2Te3
CeTe
Ce2Te3
PrTe
Pr2Te3
NdTe
Nd2Te3
Pm SmTe
Sm2Te3
EuTe
Eu2Te3
GdTe
Gd2Te3
TbTe
Tb2Te3
DyTe
Dy2Te3
HoTe
Ho2Te3
ErTe
Er2Te3
TmTe
Tm2Te3
YbTe
Yb2Te3
** Ac ThTe2 Pa UTe2 Np Pu Am Cm Bk Cf Es Fm Md No
Stub icon

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.

  • v
  • t
  • e