| Rank | Player | Pos | Team(s) played for (years) | Free
throw
percentage |
| 1 | Elena Delle Donne^ | SG / SF | Chicago Sky (2013–2016)
Washington Mystics (2017-present) | .9370 |
| 2 | Sabrina Ionescu^ | PG | New York Liberty (2020-present) | .9085 |
| 3 | Shatori Walker-Kimbrough^ | SG | Washington Mystics (2017-2019)
Phoenix Mercury (2020
Connecticut Sun (2021
Washington Mystics (2021-present) | .9065 |
| 4 | Becky Hammon* | PG | New York Liberty (1999-2006)
San Antonio Stars (2007-2014) | .8968 |
| 5 | Kayla McBride^ | SG | San Antonio Stars (2014-2017)
Las Vegas Aces (2018-2020)
Minnesota Lynx (2021-present) | .8950 |
| 6 | Allie Quigley | PG/SG | Phoenix Mercury (2008-2009)
Indiana Fever (2010)
San Antonio Silver Stars (2010)
Seattle Storm (2011)
Chicago Sky (2013-2022) | .8928 |
| 7 | Kara Lawson | PG | Sacramento Monarchs (2003-2009)
Connecticut Sun (2010-2013)
Washington Mystics (2014-2015) | .8898 |
| 8 | Tiffany Mitchell^ | SG | Indiana Fever (2016-2022)
Minnesota Lynx (2023-present) | .8889 |
| 9 | Kelsey Plum^ | SG | San Antonio Stars (2017)
Las Vegas Aces (2018-present) | .8860 |
| 10 | Jewell Loyd^ | PG/SG | Seattle Storm (2015–present) | .8851 |
| 11 | Nicole Powell | SG/SF | Charlotte Sting (2004)
Sacramento Monarchs (2005-2009)
New York Liberty (2010-2012)
Tulsa Shock (2013)
Seattle Storm(2014) | .8818 |
| 12 | Kristi Toliver | PG/SG | Chicago Sky (2009)
Los Angeles Sparks (2010-2016)
Washington Mystics (2017-2019)
Los Angeles Sparks (2021-2022)
Washington Mystics (2023-present) | .8790 |
| 13 | Cynthia Cooper* | PG/SG | Houston Comets (1997-2000)
Houston Comets (2003 | .8713 |
| 14 | Diana Taurasi^ | PG/SG | Phoenix Mercury (2004-present)
| .8706 |
| 15 | Chelsea Gray^ | PG | Connecticut Sun (2015)
Los Angeles Sparks (2016-2020)
Las Vegas Aces (2021-present) | .8686 |
| 16 | Penny Taylor | SF | Cleveland Rockers (2001-2003)
Phoenix Mercury (2004-2007)
Phoenix Mercury (2009-2011)
Phoenix Mercury (2013-2014)
Phoenix Mercury (2016) | .8684 |
| 17 | Janeth Arcain | SG | Houston Comets (1997-2005) | .8670 |
| 18 | Stefanie Dolson^ | C | Washington Mystics (2014-2016)
Chicago Sky (2017-2021)
New York Liberty (2022-present) | .8662 |
| 19 | Epiphanny Prince | PG | Chicago Sky (2010-2014)
New York Liberty (2015-2018)
Las Vegas Aces (2019
New York Liberty (2020-2022) | .8646 |
| 20 | Riquna Williams | PG/SG | Tulsa Shock (2012-2015)
Los Angeles Sparks (2017-2020)
Las Vegas Aces (2021-present) | .8625 |
| 21 | Danielle Robinson^ | PG | San Antonio Stars (2011-2016)
Phoenix Mercury (2017)
Minnesota Lynx (2018-2019)
Las Vegas Aces (2020)
Indiana Fever (2021-2022)
Atlanta Dream (2023-present) | .8612 |
| 22 | Shenise Johnson | PG/SG | San Antonio Stars (2012-2014)
Indiana Fever (2015-2019)
Minnesota Lynx (2020) | .8606 |
| 22 | Satou Sabally^ | SF | Dallas Wings (2020-present) | .8606 |
| 24 | Maya Moore | SF | Minnesota Lynx (2011-2018) | .8599 |
| 25 | DeWanna Bonner^ | SG/SF | Phoenix Mercury (2009-2019)
Connecticut Sun (2020-present) | .8591 |
