Nernst effect

Thermoelectric effect
Principles
  • Thermoelectric effect
    • Seebeck effect
    • Peltier effect
    • Thomson effect
    • Seebeck coefficient
  • Ettingshausen effect
  • Nernst effect
Applications
  • Thermoelectric materials
  • Thermocouple
  • Thermopile
  • Thermoelectric cooling
  • Thermoelectric generator
  • Radioisotope thermoelectric generator
  • Automotive thermoelectric generator

In physics and chemistry, the Nernst effect (also termed the first Nernst–Ettingshausen effect, after Walther Nernst and Albert von Ettingshausen) is a thermoelectric (or thermomagnetic) phenomenon observed when a sample allowing electrical conduction is subjected to a magnetic field and a temperature gradient normal (perpendicular) to each other. An electric field will be induced normal to both.

This effect is quantified by the Nernst coefficient ν {\displaystyle \nu } , which is defined to be

ν = E y B z 1 x T {\displaystyle \nu ={\frac {E_{y}}{B_{z}}}{\frac {1}{\partial _{x}T}}}

where E y {\displaystyle E_{y}} is the y-component of the electric field that results from the magnetic field's z-component B z {\displaystyle B_{z}} and the x-component of the temperature gradient x T {\displaystyle \partial _{x}T} .

The reverse process is known as the Ettingshausen effect and also as the second Nernst–Ettingshausen effect.

Physical picture

Mobile energy carriers (for example conduction-band electrons in a semiconductor) will move along temperature gradients due to statistics[dubious – discuss] and the relationship between temperature and kinetic energy. If there is a magnetic field transversal to the temperature gradient and the carriers are electrically charged, they experience a force perpendicular to their direction of motion (also the direction of the temperature gradient) and to the magnetic field. Thus, a perpendicular electric field is induced.

Sample types

The semiconductors exhibit the Nernst effect, as first observed by T. V. Krylova and Mochan in the Soviet Union in 1955.[1][non-primary source needed] In metals however, it is almost non-existent.[citation needed]

Superconductors

Nernst effect appears in the vortex phase of type-II superconductors due to vortex motion.[2][3][4] High-temperature superconductors exhibit the Nernst effect both in the superconducting and in the pseudogap phase.[5] Heavy fermion superconductors can show a strong Nernst signal which is likely not due to the vortices.[6]

See also

References

  1. ^ Krylova, T. V.; Mochan, I. V. (1955). "Investigation of the Nernst effect of germanium". J. Tech. Phys. 25 (12): 2119–2121.
  2. ^ Huebener, R. P.; Seher, A. (1969-05-10). "Nernst Effect and Flux Flow in Superconductors. I. Niobium". Physical Review. 181 (2): 701–709. doi:10.1103/PhysRev.181.701. ISSN 0031-899X.
  3. ^ Huebener, R. P.; Seher, A. (1969-05-10). "Nernst Effect and Flux Flow in Superconductors. II. Lead Films". Physical Review. 181 (2): 710–716. doi:10.1103/PhysRev.181.710. ISSN 0031-899X.
  4. ^ Rowe, V. A.; Huebener, R. P. (1969-09-10). "Nernst Effect and Flux Flow in Superconductors. III. Films of Tin and Indium". Physical Review. 185 (2): 666–671. doi:10.1103/PhysRev.185.666. ISSN 0031-899X.
  5. ^ Xu, Z. A.; Ong, N. P.; Wang, Y.; Kakeshita, T.; Uchida, S. (2000-08-03). "Vortex-like excitations and the onset of superconducting phase fluctuation in underdoped La2-xSrxCuO4". Nature. 406 (6795): 486–488. doi:10.1038/35020016. ISSN 0028-0836.
  6. ^ Bel, R.; Behnia, K.; Nakajima, Y.; Izawa, K.; Matsuda, Y.; Shishido, H.; Settai, R.; Onuki, Y. (2004-05-27). "Giant Nernst Effect in ${\mathrm{CeCoIn}}_{5}$". Physical Review Letters. 92 (21): 217002. arXiv:cond-mat/0311473. doi:10.1103/PhysRevLett.92.217002.
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