Nitride chloride

A chloride nitride is a mixed anion compound containing both chloride (Cl⁻) and nitride ions (N³⁻). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.^[1]

The group 4 element chloride nitrides can be intercalated by alkali metals that supply extra electrons, and other molecules such as from solvents like tetrahydrofuran, yielding layered substances that are superconductors. A superconductor transition temperature T_c of 25.5K has been achieved.^[2]

Production

Nitride chlorides may be produced by heating metal nitrides with metal chlorides. The ammonolysis process heats a metal chloride with ammonia.^[3] A related method heats a metal or metal hydride with ammonium chloride. The nitrogen source could also be an azide or an amide.^[3]

List

name	formula	formula weight	crystal system	space group	unit cell Å	volume	density	comments	ref
	Li₄NCl		hexagonal	R3	a=366.225 c=1977.18 Z=3				^[4]
	Li_1.8N_0.4Cl_0.6							Li ion conductor	^[5]
Cyanogen chloride	ClCN							molecular
Magnesium nitride chloride	Mg₂NCl		hexagonal	R3m	a = 3.2994 c = 17.857				^[6]
phosphonitrilic chloride cyclic trimer	P₃N₃Cl₆							molecular
trithiazyl trichloride	S₃N₃Cl₃							cas 5964-00-1	^[7]
	Ca₂NCl		hexagonal	R3m	a 3.6665 c 19.7187				^[8]
	Sc₂Cl₂N			P3m1	a = 3:517 c = 8.813			layered	^[1]
	Sc₄Cl₆N		orthorhombic	Pbam	a = 11.625, b = 12.118, c = 3.5447				^[1]
	Sc₅Cl₈N			C2/m	a = 17.85, b = 3.5505, c = 12.090, β = 130.13				^[1]
	Sc₇Cl₁₂N			R3	a = 12.990, c = 8.835			Sc₆N clusters	^[1]
Titanium nitride chloride	TiNCl		orthorhombic	Pmmn	a=3.275 b=3.967 c=8.402 a = 3.937, b = 3.258, c = 7.803	109.2		black	^[9]
	Li0.6TiNCl								^[9]
	Cl₃VNCl		triclinic	P1	a = 7.64, b = 7.14, c = 5.91, α = 94.9, β = 112.4, γ = 107.8			V=NCl complex	^[1]
	Zn₂NCl	180.20	orthorhombic	Pna2₁	a=6.137 b=7.394 c=5.940 Z=4	269.5	4.441	band gap 3.21 eV	^[10]
	Zn₂NCl		orthorhombic	Pnma	Z=16			predicted	^[11]
	Zn₂NCl		hexagonal	R3m				predicted	^[11]
	Sr₂BN₂Cl								^[12]
	α-Y₂Cl₃N		orthorhombic	Pbcn	a = 12.761, b = 6.676, c = 6.1000				^[1]
	β-Y₂Cl₃N			C2/m	a = 15.248, b = 3.8520, c = 10.157, β = 118.41				^[1]
	α-ZrNCl		orthorhombic	Pmmn	a = 3.937, b = 3.258, c = 7.803			pale yellow-green	^[1]
β-zirconium nitride chloride	β-ZrNCl		hexagonal	R3m	a = 3.6031, c = 27.672			yellow-green;semiconductor; layers of Cl–Zr–N–N–Zr–Cl	^[13]^[1]
	Zr₆Cl₁₅N		cubic	Ia3d	a = 21.171				^[1]
Lithium-intercalated β-zirconium nitride chloride	Li_xZrNCl							black; superconductor T_c=12.5 K	^[14]
	Na_xZrNCl							superconductor T_c 15 K	^[13]
	K_xZrNCl							superconductor T_c 15 K	^[13]
molybdenum nitride chloride	MoNCl₃		triclinic	P1	a = 9.14, b = 7.67, c = 8.15, α = 108.8, β = 99.3, γ= 108.6				^[15]^[1]
	Mo₂NCl₇		triclinic	P1	a = 9.057, b = 9.754, c = 12.834, α = 103.13, β = 109.83, γ = 98.58				^[1]
	Mo₂NCl₈		monoclinic	P2/c	a = 9.961, b = 6.294, c = 17.808, β = 101.82				^[1]
Phenyldiazonium tetrachloronitridomolybdate	C₆H₅N₂[MoNCl₄]		monoclinic	P2₁/c	a = 12.83, b = 11.70, c = 19.22 β = 94.11 Z=2			dark red	^[15]
Technetium chloride nitride	TcCl₃N							black; cas 154525-32-3	^[7]
	(Ph₄As)[TcNCl₄]								^[16]
	[Se₃N₂Cl]⁺SbCl₆^-		triclinic	P1	a=6.982 b=6.997 c=15.105 α = 89.45°, β = 86.18°, γ = 68.22° Z=2			red	^[17]
	Ba₂NCl		hexagonal	R3m
	Ba₃Si₃N₅OCl			P62c	a=9.560 c=5.552				^[18]
	Ba₂₅Nb₅N₁₉Cl₁₈								^[1]
	LiBa₄[Mo₂N₇]BaCl₂								^[1]
	La₂NCl₃		orthorhombic	Ibam	a = 13.758, b = 6.922, c = 6.185				^[19]
	La₂Cl(CN₂)N		orthorhombic	Cmmm	a = 13.340, b = 9.5267, c = 3.9402, Z=4				^[20]
	La₆N₃S₄Cl		orthorhombic	Pnma	a = 11.597; b = 4.1095; c = 27.568 Z=4				^[21]
	CeNCl		tetragonal	P4/nmm	a=4.079 c=6.837 Z=			black	^[22]
Cerium(III) nitride chloride	Ce₂NCl₃		orthorhombic	Ibam	a = 13.6021 b=6.8903 c= 6.1396 Z=4	575.42	4.624	Light yellow	^[23]
	Ce₂Cl(CN₂)N		orthorhombic	Cmmm	a = 13.3914, b = 9.6345, c = 3.9568, Z=4				^[20]
	Ce₆Cl₁₂N₂	1294.1	monoclinic	P2₁/c	a=11.233 b=16.527 c=10.798 β =90.15 Z=4	1988	4.324	yellow	^[22]
	Na₂[{(ON)Ce₄}Cl₉]		monoclinic	P2₁/m	a = 8.1321, b = 11.4613, c = 9.4286 and β = 107.504° Z=2				^[24]
	Pr₂NCl₃		orthorhombic	Ibam	a = 13.531, b = 6.8512, c = 6.1072				^[19]
	Pr₅N₃S₂Cl₂		monoclinic	C2/m	a = 15.402; b = 4.0092; c = 16.563; β = 101.24°, Z = 4				^[25]
	Pr₆N₃S₄Cl		orthorhombic	Pnma	a=11.3987 b=4.0235 c=26.999 Z=4	1238.3		reddish-brown	^[26]
	Nd₂NCl₃		orthorhombic	Pbcn	a = 13.382, b = 6.8462, c = 6.1815				^[19]
	Nd₃NCl₆		orthorhombic	Pbca	a = 10.4971, b = 11.0683, c = 16.211; Z = 8				^[27]
	Nd₄NS₃Cl₃		hexagonal	P6₃mc	a = 9.2278, c = 6.8306; Z = 2				^[27]
	Nd₆N₃S₄Cl		orthorhombic	Pnma	a = 11.371; b = 3.9934; c = 26.876				^[21]
	Na₂Nd₄ONCl₉		monoclinic	P2₁/m	a = 8.0354, b = 11.3426, c = 9.2831 and β = 107.109°				^[28]
Trigadolinium hexachloride nitride	Gd₃Cl₆N	698.485	triclinic	P1	a = 7.107, b = 8.156, c = 9.707, α = 75.37°, β = 109.10°, γ = 114.64° Z=2	478.8	4.84	colourless; water sensitive; biaxial (−)	^[29]
	Gd₂NCl₃		orthorhombic	Pbcn	a=13.017 b=6.7310 c=6.1403				^[19]
	Gd₂N₂Cl		tetragonal	P4mm	a = 4.25 c = 5.92				^[30]
	α-HfNCl		orthorhombic	Pmmn	a = 4.130, b = 3.497, c = 8.070				^[31]^[1]
	β-HfNCl		hexagonal	R3m	a = 3.5744, c = 27.7075			colourless	^[1]
	Na_xHfNCl							superconductor T_c 25 K	^[32]
	Ba₃Ta₃N₆Cl			P62c	a =10.1455 c =5.9770				^[18]
	Ba₃Cl₂TaN₃		hexagonal	P6₃cm	a = 15.0739, c = 6.3298; Z = 6			light yellow	^[33]
	Ba₁₅Ta₁₅N₃₃Cl₄			P62c	a =10.1545 c =29.917				^[18]
	W₂NCl₈		triclinic	P1	a = 6.2423, b = 6.309, c = 6.931, α = 89.76, β = 81.51, γ = 82.68				^[1]
	W₂NCl₉			P2₁/c	a = 8.421, b = 16.786, c = 11.930, β = 134.74°				^[1]
	[WNCl₃ • POCl₃]₄ • 2 POCl₃		triclinic	P1	a = 12.257 b = 11.851 c = 19.27.0 α = 102.6° β= 108.4° γ = 94.8° Z=2				^[34]
	Ba₄[WN₄]Cl₂								^[1]
	ReNCl₄		tetragonal	I4	a=8.278 b=8.281 c=4.057 Z=2			brown	^[35]^[36]
	ReNCl₄·H₂O		orthorhombic	Pnma	a = 10.754, b = 11.085, c = 547.7 Z=4			red	^[36]
	[NBu₄][ReNCl₄]		orthorhombic	P4/n	a 11.795 b 11.795 c 8.466			ReN triple bond in complex	^[37]
	K₂OsNCl₅		orthorhombic	Pnma	a = 13.27, b = 9.85, c = 6.84				^[1]
Kleinite	Hg2N(Cl,SO4)•n(H2O)		hexagonal	C6₃/mmc	a = 13.56 c = 11.13 Z = 18	1,772.33	8.01	yellow	^[38]
Mosesite	Hg2N(Cl,SO4,MoO4,CO3)•(H2O)		cubic	F43m	a = 9.524, Z = 8	863.89	7.71	yellow; refractive index 2.065	^[39]
	ThNCl		tetragonal	P4/nmm	a =4.09486 c =6.9013				^[40]
Uranium nitride chloride	UNCl		tetragonal	P4/nmm	a=3.97 c=6.81 Z=2				^[41]

References

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