Nitronium tetrafluoroborate
Names | |
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Other names nitronium fluoroborate, NO 2BF 4 | |
Identifiers | |
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ECHA InfoCard | 100.034.107 |
EC Number |
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PubChem CID |
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InChI
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Properties | |
Chemical formula | BNO2F4 |
Molar mass | 132.81 |
Hazards | |
GHS labelling: | |
Pictograms | |
Danger | |
Hazard statements | H314, H317, H334 |
Precautionary statements | P260, P261, P264, P272, P280, P285, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P310, P321, P333+P313, P342+P311, P363, P405, P501 |
Safety data sheet (SDS) | [1] |
Related compounds | |
Other cations | Nitrosonium tetrafluoroborate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y verify (what is YN ?) Infobox references |
Chemical compound
Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents.
Preparation
Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide.[1]
Applications
Nitronium tetrafluoroborate is used as a nitration agent.
References
- ^ Kenneth Schofield (1980). Aromatic nitration. CUP Archive. p. 88. ISBN 0-521-23362-3.
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Salts and covalent derivatives of the tetrafluoroborate ion
HBF4 | He | ||||||||||||||||||||
LiBF4 | Be | B | C7H7BF4 [Et3O]BF4 [Me3O]BF4 (FTEDA)BF4 | NOBF4 NO2BF4 NH4BF4 | O | F | Ne | ||||||||||||||
NaBF4 | Mg(BF4)2 | Al | Si | P | S | Cl | Ar | ||||||||||||||
KBF4 | Ca(BF4)2 | Sc | Ti | V | [Cr(MeCN)6](BF4)3 [Cr(MeCN)4](BF4)2 | Mn(BF4)2 | Fe(BF4)2 FeO(BF4)2 [FeCp2]BF4 | Co(BF4)2 | Ni(BF4)2 [Ni(MeCN)6](BF4)2 | Cu(BF4)2 | Zn(BF4)2 | Ga | Ge | As | Se | Br | Kr | ||||
RbBF4 | Sr(BF4)2 | Y | Zr | Nb | [Mo2(MeCN)8](BF4)4 [Mo2(MeCN)10](BF4)4 | [Tc2(MeCN)10](BF4)4 | [Ru(MeCN)6](BF4)2 | [Rh(MeCN)6](BF4)3 [Rh2(MeCN)10](BF4)4 | [Pd(MeCN)4](BF4)2 | AgBF4 | Cd(BF4)2 | In(BF4)3 | Sn(BF4)2 | Sb | Te | (IPy2)BF4 | Xe | ||||
CsBF4 | Ba(BF4)2 | * | Lu | Hf | Ta | W | Re | Os | Ir | Pt(BF4)2 | Au | Hg(BF4)2 | TlBF4 | Pb(BF4)2 | Bi | Po | At | Rn | |||
Fr | Ra | ** | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
* | La | Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | |||||||
** | Ac | Th | Pa | U | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No |