Organokrypton chemistry
Study of the carbon-krypton bond
Organokrypton chemistry describes the synthesis and properties of organokrypton compounds, chemical compounds containing a carbon to krypton chemical bond.
Far fewer such compounds are known than organoxenon compounds. The first organokrypton compound, HKrCCH, was reported in 2003 and made by photolytic insertion of a krypton atom into acetylene.[1] Similar work was then done on diacetylene and cyanoacetylene, producing HKrC4H and HKrC3N.[2] All these were made in matrix isolation and are stable up to 40 K.[3] HKrCCF and HCCKrF have also been experimentally produced in matrix isolation.[4]
Dications generated by dissociative electron ionisation of 2,4,6-trimethylpyridine react with krypton to form the organokrypton cations C8H7NKr2+ and C8H8NKr2+.[5] Reaction of acetylene dications with krypton produced HCCKr2+.[6]
References
- ^ Khriachtchev, Leonid; Tanskanen, Hanna; Cohen, Arik; Gerber, R. Benny; Lundell, Jan; Pettersson, Mika; Kiljunen, Harri; Räsänen, Markku (2003). "A Gate to Organokrypton Chemistry: HKrCCH". Journal of the American Chemical Society. 125 (23): 6876–6877. doi:10.1021/ja0355269. PMID 12783534.
- ^ Khriachtchev, Leonid; Räsänen, Markku; Gerber, R. Benny (2009). "Noble-Gas Hydrides: New Chemistry at Low Temperatures". Accounts of Chemical Research. 42 (1): 183–191. doi:10.1021/ar800110q. PMID 18720951.
- ^ Bartlett, Neil (2003). "The Noble Gases". Chemical and Engineering News. 81 (36): 32–34. doi:10.1021/cen-v081n036.p032.
- ^ Khriachtchev, Leonid; Domanskaya, Alexandra; Lundell, Jan; Akimov, Alexander; Räsänen, Markku; Misochko, Eugenii (2010). "Matrix-Isolation and ab Initio Study of HNgCCF and HCCNgF Molecules (Ng = Ar, Kr, and Xe)". The Journal of Physical Chemistry A. 114 (12): 4181–4187. Bibcode:2010JPCA..114.4181K. doi:10.1021/jp1001622. hdl:10138/23938. PMID 20205379.
- ^ Zins, Emilie-Laure; Schröder, Detlef (2011). "Influence of the structure of medium-sized aromatic precursors on the reactivity of their dications towards rare gases". International Journal of Mass Spectrometry. 299 (1): 53–58. Bibcode:2011IJMSp.299...53Z. doi:10.1016/j.ijms.2010.09.017.
- ^ Ascenzi, Daniela; Tosi, Paolo; Roithová, Jana; Ricketts, Claire L.; Schröder, Detlef; Lockyer, Jessica F.; Parkes, Michael A.; Price, Stephen D. (2008). "Generation of the organo-rare gas dications HCCRg2+ (Rg = Ar and Kr) in the reaction of acetylene dications with rare gases". Physical Chemistry Chemical Physics. 10 (47): 7121–7128. Bibcode:2008PCCP...10.7121A. doi:10.1039/B810398D. PMID 19039346.
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Compounds of carbon with other elements in the periodic table
| CH | He | |||||||||||||||||
| CLi | CBe | CB | CC | CN | CO | CF | Ne | |||||||||||
| CNa | CMg | CAl | CSi | CP | CS | CCl | CAr | |||||||||||
| CK | CCa | CSc | CTi | CV | CCr | CMn | CFe | CCo | CNi | CCu | CZn | CGa | CGe | CAs | CSe | CBr | CKr | |
| CRb | CSr | CY | CZr | CNb | CMo | CTc | CRu | CRh | CPd | CAg | CCd | CIn | CSn | CSb | CTe | CI | CXe | |
| CCs | CBa |  | CLu | CHf | CTa | CW | CRe | COs | CIr | CPt | CAu | CHg | CTl | CPb | CBi | CPo | CAt | Rn |
| Fr | CRa |  | Lr | Rf | Db | CSg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og |
| | CLa | CCe | CPr | CNd | CPm | CSm | CEu | CGd | CTb | CDy | CHo | CEr | CTm | CYb | ||||
| | Ac | CTh | CPa | CU | CNp | CPu | CAm | CCm | CBk | CCf | CEs | Fm | Md | No | ||||
- Chemical bonds to carbon
- Core organic chemistry
- Many uses in chemistry
- Academic research, no widespread use
- Bond unknown
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