Phosphide chloride

A Phosphide chloride is a mixed anion compound containing both phosphide (P3−) and chloride (Cl−) ions.

A common structural element is P73− which is called heptaphosphanortricyclane with a formal IUPAC name of heptaphosphatricyclo[2.2.1.02,6]heptane.[1]

Group 12 elements, cadmium and mercury are in most of the known compounds.

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Ca3PCl3 cubic Pm3m a=5.713 Z=1 186.48 2.29 [2]
Cu6PS5Cl 607.96 cubic P43m a=9.6962 Z=4 911.6 4.430 red [3]
Sr2PCl cubic a=6.18 [4]
Sr2P7Cl monoclinic C2/c a=14.571 b=12.212 c=22.292 β=103.740° Z=16 3853 3.948 P73–, clusters [1]
Ag6PS5Cl cubic P43m a=10.3514 Z=4 1109.2 5.234 orange [3]
α-Cd3PCl3 hexagonal a=7.63 c=7.13 pale yellow >530 °C or quenched [5]
β-Cd3PCl3 monoclinic a=6.99 b=7.97 c=7.38 β=118.1° pale yellow <530 °C [5]
Cd4P2Cl3 617.89 cubic Pa3 a=12.1474 Z=8 1792.5 4.579 yellow; band gap 2.36 eV [6]
Cd2P3Cl monoclinic C2/c a=7.98 b=8.98 c=7.55 β= brown; band gap 1.87 [7]
Cd2PCl2 monoclinic P21/n a=7.736 b=8.957 c=7.880 β=118.92° Z=4 477.93 4.540 yellow [8][9]
Cd7P4Cl6 cubic Pa3 a=11.93 light green [7]
Ba2P7Cl monoclinic P21/m a = 11.726, b = 6.829, c = 6.337, β = 95.27°, Z = 2 P73–, clusters [1][10]
La3Zn4P6Cl orthorhombic Cmcm a= 4.0576 b 13.632 c 21.547 Z=4 1191.8 5.013 black; thermal conductivity 0.7 Wm−1 K−1 (low) [11][12]
Eu2PCl cubic Fm3m a = 6.106, Z = 2 [13]
W6PCl17 orthorhombic Imm2 a=6.7835 b=15.8762 c=10.0727 Z=2 1084.79 5.3168 black [14]
W4(PCl)Cl10 monoclinic C2/m a=13.257 b=9.850 c=11.400 β=91.38 Z=4 1488.2 5.161 black; chloro-phosphinidene ligand [14]
[Hg4P2][HfCl6] orthorhombic Pbca a=12.919 b=13.263 c=16.239 Z=8 2783 5.994 yellow [15]
Hg2PCl2 monoclinic I2/m a=7.643,b=7.977,c=8.539,β=115.23°,Z=4 469.8 7.113 yellow [16][17]
Hg2P3Cl monoclinic C2/c a = 7.834, b = 8.844, c = 7.591, β = 98.68°, Z = 4 [18]
[Hg6P4](TiCl6)Cl cubic Pa3 a=11.7675, Z=4 1627.2 6.627 black or dark brown [19]
(Hg6P4)(CrCl6)Cl 1627.57 cubic Pa3 a=11.7364 Z=4 1616.6 6.687 yellow; resistivity is humidity sensitive [20]
(Hg6P4)(CuCl3)2 monoclinic C2/c a=23.633 b=8.956 c=14.248 β =124.213° Z=6 2493.9 6.660 pinkish-red; ferroelectric below 37 K: 114 μC m−2 [21]
(Hg23P12)(ZnCl4)6 hexagonal P62m a=12.9774 c=11.749 Z=1 1713.6 6.035 yellow [22]
(Hg11P4)(GaCl4)4 monoclinic C2/m a=12.762 b=7.353 c=22.040 β=100.32 Z=2 2034.7 5.185 yellow [23]
[Hg4P2][ZrCl6] orthorhombic Pbca a=12.899 b=13.255 c=16.196 Z=8 2769.1 5.604 yellow [15]
Hg4Ag5P8Cl5 orthorhombic Cmcm a=11.1426 b=14.5064 c=11.8444 Z=4 1914.5 6.129 high temp [24]
Hg4Ag5P8Cl5 monoclinic C2/m a=14.490 b=10.904 c=6.2863 β=104.094 Z=2 963.4 6.090 [24]
[Hg6P4Cl3](SnCl3) cubic P213 a = 11.865 Z=4 [25]
(Hg6P4Cl3)(PbCl3) cubic P213 a=11.8837 Z=4 1678.24 6.916 yellow [22]

References

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  2. ^ Hadenfeldt, C.; Herdejürgen, H. (October 1986). "Darstellung, kristallstruktur und thermisches verhalten der calciumphosphidchloride Ca2 − xP1 − xCl1+x (0 ⩽ x ⩽ 0,18) und Ca3PCl3". Journal of the Less Common Metals (in German). 124 (1–2): 93–103. doi:10.1016/0022-5088(86)90480-7.
  3. ^ a b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.
  4. ^ Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3". Zeitschrift für Naturforschung B. 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. S2CID 95122668.
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  10. ^ Schnering, Hans Georg V.; Menge, Günter (October 1981). "Zur Chemie und Strukturchemie der Phosphide und Polyphosphide. 26. Dibariumheptaphosphidchlorid Ba2P7Cl, eine Verbindung mit dem polycyclischen Anion P73?". Zeitschrift für anorganische und allgemeine Chemie. 481 (10): 33–40. doi:10.1002/zaac.19814811005.
  11. ^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
  12. ^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.
  13. ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
  14. ^ a b Ströbele, Markus; Eichele, Klaus; Meyer, H.‐Jürgen (September 2011). "Phosphorus‐Centered and Phosphinidene‐Capped Tungsten Chloride Clusters". European Journal of Inorganic Chemistry. 2011 (26): 4063–4068. doi:10.1002/ejic.201100122. ISSN 1434-1948.
  15. ^ a b Li, Xiao‐Guo; Jiang, Xiao‐Ming; Zhang, Ming‐Jian; Liu, Bin‐Wen; Fan, Yu‐Hang; Guo, Guo‐Cong; Huang, Jin‐Shun (2013-12-02). "Three‐Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)". European Journal of Inorganic Chemistry. 2013 (35): 5980–5986. doi:10.1002/ejic.201300888. ISSN 1434-1948.
  16. ^ Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (14 May 2014). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. p. 207. ISBN 978-3-13-179211-2.
  17. ^ Olenev, Andrei V.; Shevelkov, Andrei V.; Popovkin, Boris A. (January 1999). "Crystal Structure of Hg2PCl2and Electronic Structure of Its Main "Building Unit"—The (P2Hg6) Octahedron". Journal of Solid State Chemistry. 142 (1): 14–18. Bibcode:1999JSSCh.142...14O. doi:10.1006/jssc.1998.7977.
  18. ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
  19. ^ Olenev, Andrei V.; Shevelkov, Andrei V. (August 2001). "Synthesis, Structure, and Properties of [Hg6P4](TiCl6)Cl: The Problem of Host–Guest Interactions". Journal of Solid State Chemistry. 160 (1): 88–92. Bibcode:2001JSSCh.160...88O. doi:10.1006/jssc.2001.9196.
  20. ^ Peng, Si-Yan; Yang, Liu-Sai; Yao, Ming-Shui; Yu, Le-Shu (2018). "A new pnictidehalide with van der Waals host–guest interactions exhibiting both geometric spin frustration and resistive humidity sensitivity". New Journal of Chemistry. 42 (3): 1787–1795. doi:10.1039/C7NJ03351F. ISSN 1144-0546.
  21. ^ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Jing-Xue; Liu, Mei-Feng; Guo, Guo-Cong; Jin, Biao-Bing; Li, Xiao-Guang; Liu, Jun-Ming (December 2013). "Ferroelectric Transition in the Inorganic Supramolecular Complex (Hg 6 P 4 )(CuCl 3 ) 2". Chemistry: An Asian Journal. 8 (12): 2925–2931. doi:10.1002/asia.201301040. PMID 24006192.
  22. ^ a b Jiang, Xiao-Ming; Wang, Guan-E; Liu, Zhi-Fa; Zhang, Ming-Jian; Guo, Guo-Cong (2013-08-05). "Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption". Inorganic Chemistry. 52 (15): 8865–8871. doi:10.1021/ic401056t. ISSN 0020-1669. PMID 23837877.
  23. ^ Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013). "New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)". Dalton Transactions. 42 (43): 15475–15481. doi:10.1039/c3dt51451j. ISSN 1477-9226. PMID 24022795.
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  25. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
  • v
  • t
  • e
Phosphides
Binary phosphides
PH3 He
Li3P Be BP CP
+C 		N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP 		P S +Cl Ar
K3P Ca3P2
CaP 		ScP TiP V CrP
Cr3P 		Mn FeP CoP
Co2P
Co3P2 		NixPy Cu3P Zn3P2
ZnP2 		GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2 		NbP Mo3P
MoP
MoP2 		Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* LaP CeP PrP
PrP5 		NdP Pm SmP
SmP5 		EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphidesQuaternary phosphidesQuinary phosphidesSee also
  • v
  • t
  • e
Salts and covalent derivatives of the chloride ion
HCl He
LiCl BeCl2 B4Cl4
B12Cl12
BCl3
B2Cl4
+BO3 		C2Cl2
C2Cl4
C2Cl6
CCl4
+C
+CO3 		NCl3
ClN3
+N
+NO3 		ClxOy
Cl2O
Cl2O2
ClO
ClO2
Cl2O4
Cl2O6
Cl2O7
ClO4
+O 		ClF
ClF3
ClF5 		Ne
NaCl MgCl2 AlCl
AlCl3 		Si5Cl12
Si2Cl6
SiCl4 		P2Cl4
PCl3
PCl5
+P 		S2Cl2
SCl2
SCl4
+SO4 		Cl2 Ar
KCl CaCl
CaCl2 		ScCl3 TiCl2
TiCl3
TiCl4 		VCl2
VCl3
VCl4
VCl5 		CrCl2
CrCl3
CrCl4 		MnCl2
MnCl3 		FeCl2
FeCl3 		CoCl2
CoCl3 		NiCl2 CuCl
CuCl2 		ZnCl2 GaCl
GaCl3 		GeCl2
GeCl4 		AsCl3
AsCl5
+As 		Se2Cl2
SeCl2
SeCl4 		BrCl Kr
RbCl SrCl2 YCl3 ZrCl3
ZrCl4 		NbCl3
NbCl4
NbCl5 		MoCl2
MoCl3
MoCl4
MoCl5
MoCl6 		TcCl3
TcCl4 		RuCl2
RuCl3
RuCl4 		RhCl3 PdCl2 AgCl CdCl2 InCl
InCl2
InCl3 		SnCl2
SnCl4 		SbCl3
SbCl5 		Te3Cl2
TeCl2
TeCl4 		ICl
ICl3 		XeCl
XeCl2
XeCl4
CsCl BaCl2 * LuCl3 HfCl4 TaCl3
TaCl4
TaCl5 		WCl2
WCl3
WCl4
WCl5
WCl6 		ReCl3
ReCl4
ReCl5
ReCl6 		OsCl2
OsCl3
OsCl4
OsCl5 		IrCl2
IrCl3
IrCl4 		PtCl2
PtCl4 		AuCl
(Au[AuCl4])2
AuCl3 		Hg2Cl2
HgCl2 		TlCl
TlCl3 		PbCl2
PbCl4 		BiCl3 PoCl2
PoCl4 		AtCl Rn
FrCl RaCl2 ** LrCl3 RfCl4 DbCl5 SgO2Cl2 BhO3Cl Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaCl3 CeCl3 PrCl3 NdCl2
NdCl3 		PmCl3 SmCl2
SmCl3 		EuCl2
EuCl3 		GdCl3 TbCl3 DyCl2
DyCl3 		HoCl3 ErCl3 TmCl2
TmCl3 		YbCl2
YbCl3
** AcCl3 ThCl3
ThCl4 		PaCl4
PaCl5 		UCl3
UCl4
UCl5
UCl6 		NpCl3 PuCl3 AmCl2
AmCl3 		CmCl3 BkCl3 CfCl3
CfCl2 		EsCl2
EsCl3 		FmCl2 MdCl2 NoCl2