Phosphide silicide

Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, germanide phosphides, nitride silicides, and antimonide silicides.

One preparation method is to heat a metal phosphide with silicon in a silica tube. Phosphorus must be prevented from evaporating. Another method is to use a liquid tin flux.

Phosphide silicides may be present as minerals. They are under investigation as photovoltaic materials.[1]

List

formula system space group unit cell Å volume density comment ref
Li10.68Si5P orthorhombic Pnma a = 10.2434, b = 4.2788, c = 23.9767 Z=4 1050.89 1.52 grey metallic; Si5 rings [2]
Fe5PSi hexagonal P63cm a=6.766 c=12.456 Z=6 493.83 6.82 [3]
Fe5(P,Si)3 [4]
Fe7(P,Si)3 [5]
(Fe,Ni)8(P,Si)3 Perryite [6]
Ni2PSi orthorhombic Pbca a=4.985 b=5.871 c=13.667 399.95 5.86 [7]
ZrCuSiP P4/nmm a=3.5671 c=9.4460 metallic [8]
La4(P1−xSix)3-z cubic I43d [9]
Ce4(P1−xSix)3-z cubic I43d [9]
Ce4P1.77Si1.23 cubic I43d a=8.9359 Z=4 713.53 6.0474 black [9]
Pr4(P1−xSix)3-z cubic I43d [9]
Nd4(P1−xSix)3-z cubic I43d [9]
Gd4Co13(Si, P)9 P6m2 a = 10.419, c = 37.27 [10]
Sm4Co13(Si, P)9 P6m2 [10]
Tb4Co13(Si, P)9 P6m2 [10]
Dy4Co13(Si, P)9 P6m2 [10]
Ho4Co13(Si, P)9 P6m2 [10]
Er4Co13(Si, P)9 P6m2 [10]
Hf27Si6P10 Immm a = 3.5739, b = 18.623, c = 23.081, Z = 2 11.443 P2 groups [11]

References

  1. ^ Martinez, Aaron D.; Ortiz, Brenden R.; Johnson, Nicole E.; Baranowski, Lauryn L.; Krishna, Lakshmi; Choi, Sukgeun; Dippo, Patricia C.; To, Bobby; Norman, Andrew G.; Stradins, Paul; Stevanovic, Vladan (January 2015). "Development of ZnSiP$_{\mathbf 2}$ for Si-Based Tandem Solar Cells". IEEE Journal of Photovoltaics. 5 (1): 17–21. doi:10.1109/JPHOTOV.2014.2362305. ISSN 2156-3381. S2CID 6853210.
  2. ^ Fässler, Thomas Friedrich; Eickhoff, Henrik; Toffoletti, Lorenzo; Klein, Wilhelm; Raudaschl-Sieber, Gabi (2022-01-20). "Planar Si5 and Ge5 Pentagons beside Isolated Phosphide Anions in Lithium Phosphide Tetrelides Li10+xSi5P and Li10+xGe5P". Zeitschrift für anorganische und allgemeine Chemie. 648 (10): zaac.202100376. doi:10.1002/zaac.202100376. ISSN 0044-2313. S2CID 246183043.
  3. ^ Ellner, M.; El-Boragy, M. (June 1992). "Über die eisenhaltigen vertreter des strukturtyps Pd5Sb2". Journal of Alloys and Compounds (in German). 184 (1): 131–138. doi:10.1016/0925-8388(92)90461-H.
  4. ^ "Unnamed (Fe Phosphide-Silicide II)". www.mindat.org. Retrieved 2021-09-22.
  5. ^ "Unnamed (Fe Phosphide-Silicide I)". www.mindat.org. Retrieved 2021-09-22.
  6. ^ Dambaev, V. A.; Ulyanov, A. A. (March 1998). "Opaque Minerals in Enstatite Chondrites: Perryite - Silicophosphide NI and Fe in PCA 91085 and Conditions of Its Formation". Lunar and Planetary Science Conference. 29 (1282): 1282. Bibcode:1998LPI....29.1282D.
  7. ^ None Available (2017), Materials Data on SiNi2P by Materials Project, The Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States), doi:10.17188/1262921, retrieved 2021-09-22
  8. ^ Abe, Hideki; Yoshii, Kenji (May 2002). "Structure and Electrical Transport Property of a Silicopnictide ZrCuSiP". Journal of Solid State Chemistry. 165 (2): 372–374. Bibcode:2002JSSCh.165..372A. doi:10.1006/jssc.2002.9553.
  9. ^ a b c d e Chizhov, Pavel S.; Khasanova, Nellie R.; Baitinger, Michael; Schnelle, Walter; Prots, Yuri; Burkhardt, Ulrich; Antipov, Evgeny V.; Grin, Yuri (2006-09-01). "Ce 4 (P 1- x Si x ) 3- z : A First Example for the Stabilization of the Anti-Th 3 P 4 Type Structure by Substitution in the Non-Metal Substructure". Inorganic Chemistry. 45 (18): 7210–7216. doi:10.1021/ic060726h. ISSN 0020-1669. PMID 16933921.
  10. ^ a b c d e f Jeitschko, Wolfgang; Jakubowski-Ripke, Ursula; Albering, Jörg (June 2011). "Crystal Structure of the Silicide Phosphide Gd4Co13(Si, P)9, the Isotypic Lanthanoid Cobalt Silicide Phosphides Ln4Co13(Si, P)9 (Ln = Sm, Tb, Dy, Ho, Er), and the Uranium Iron Phosphide U4Fe13P9". Zeitschrift für anorganische und allgemeine Chemie. 637 (7–8): 895–900. doi:10.1002/zaac.201000404.
  11. ^ Huang, Chang-Cang; Neuhausen, Jörg; Tremel, Wolfgang (2000). "Hf27Si6P10, a novel metal-rich compound with P2 groups". Chemical Communications (1): 17–18. doi:10.1039/a906873b.
  • v
  • t
  • e
Phosphides
Binary phosphides
PH3 He
Li3P Be BP CP
+C 		N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP 		P S +Cl Ar
K3P Ca3P2
CaP 		ScP TiP V CrP
Cr3P 		Mn FeP CoP
Co2P
Co3P2 		NixPy Cu3P Zn3P2
ZnP2 		GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2 		NbP Mo3P
MoP
MoP2 		Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* LaP CeP PrP
PrP5 		NdP Pm SmP
SmP5 		EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphidesQuaternary phosphidesQuinary phosphidesSee also
  • v
  • t
  • e
Salts and covalent derivatives of the silicide ion
SiH4
+H 		He
LiSi Be2Si SiB3
SiB6
+B 		SiC
+C 		Si3N4
-N
+N 		SiO2 SiF4 Ne
NaSi Mg2Si Al Si4− SiP, SiP2
-P
+P 		SiS2
-S 		SiCl4 Ar
KSi CaSi
CaSi2 		ScSi Sc5Si3 Sc2Si3 Sc5Si4 TiSi
TiSi2 		V3Si V5Si3, V6Si5, VSi2, V6Si5 Cr3Si Cr5Si3, CrSi, CrSi2 MnSi, MnSi2, Mn9Si2, Mn3Si, Mn5Si3, Mn11Si9 FeSi2
FeSi
Fe5Si3
Fe2Si
Fe3Si 		CoSi, CoSi2, Co2Si, Co3Si NiSi, more… Cu17Si3, Cu56Si11, Cu5Si, Cu33Si7, Cu4Si, Cu19Si6, Cu3Si, Cu87Si13 Zn Ga GeSi
+Ge 		SiAs, SiAs2
-As
+As 		SiSe2 SiSe SiBr4 Kr
RbSi SrSi2 YSi Y5Si3, Y5Si4, Y3Si5, YSi1.4 ZrSi Zr5Si3, Zr5Si4, ZrSi2, Zr3Si2, Zr2Si, Zr3Si Nb4Si Nb5Si3 MoSi2
Mo3Si Mo5Si3 		Tc RuSi Ru2Si, Ru4Si3, Ru2Si3 RhSi Rh2Si, Rh5Si3, Rh3Si2, Rh20Si13 PdSi Pd5Si, Pd9Si2, Pd3Si, Pd2Si Ag Cd In Sn Sb TeSi2 Te2Si3 SiI4 Xe
CsSi Ba2Si BaSi2, Ba5Si3 Ba3Si4 * Lu5Si3 HfSi Hf2Si, Hf3Si2, Hf5Si4, HfSi2 Ta9Si2, Ta3Si, Ta5Si3 WSi2 W5Si3 ReSi Re2Si, ReSi1.8 Re5Si3 OsSi IrSi PtSi Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaSi2 La5Si3, La3Si2, La5Si4, LaSi CeSi2 Ce5Si3, Ce3Si2, Ce5Si4, CeSi, Ce3Si5 PrSi2 Pr5Si3, Pr3Si2, Pr5Si4, PrSi NdSi Nd5Si3, Nd5Si4, Nd5Si3, Nd3Si4, Nd2Si3, NdSix Pm SmSi2 Sm5Si4, Sm5Si3, SmSi, Sm3Si5 Eu? GdSi2 Gd5Si3, Gd5Si4, GdSi TbSi2 SiTb, Si4Tb5, Si3Tb5 DySi2 DySi HoSi2 Ho5Si3, Ho5Si4, HoSi, Ho4Si5 ErSi2 Er5Si3, Er5Si4, ErSi Tm? YbSi Si1.8Yb, Si5Yb3, Si4Yb3, Si4Yb5, Si3Yb5
** Ac ThSi PaSi USi2 NpSi2 PuSi Am Cm Bk Cf Es Fm Md No