Potassium fulminate

Potassium fulminate
K + C N + O {\displaystyle {\ce {\mathsf {K+^{-}C{\equiv }{\overset {+}{N}}-O^{-}}}}}
Names
IUPAC name
Potassium oxidoazaniumylidynemethane
Identifiers
CAS Number
  • 15736-99-9 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 9541865 checkY
PubChem CID
  • 15975309
CompTox Dashboard (EPA)
  • DTXSID00580534 Edit this at Wikidata
InChI
  • InChI=1S/CNO.K/c1-2-3;/q-1;+1 checkY
    Key: LOMWRVTZROPEGG-UHFFFAOYSA-N checkY
  • InChI=1/CNO.K/c1-2-3;/q-1;+1
    Key: LOMWRVTZROPEGG-UHFFFAOYAS
  • [K+].[C-]#[N+][O-]
Properties
Chemical formula
CKNO
Molar mass 81.115 g·mol−1
Density 1.8 g/cm3
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Potassium fulminate is the potassium salt of the fulminate ion. Its only use, aside from chemical demonstrations, is in the percussion caps for some early rifles. Usually prepared by reacting a potassium amalgam with mercury fulminate,[1] it is much less sensitive due to the ionic bond between potassium and carbon, unlike the weaker covalent bond between mercury and carbon.

See also

References

  1. ^ Z. Iqbal and A. D. Yoffe (1967). "Electronic Structure and Stability of the Inorganic Fulminates". Proceedings of the Royal Society of London. 302 (1468): 35–49. Bibcode:1967RSPSA.302...35I. doi:10.1098/rspa.1967.0225. S2CID 93161907.
  • v
  • t
  • e
H, (pseudo)halogens
chalcogens
  • K2O
  • KOH
  • K2O2
  • KO2
  • KO3
  • K2S
  • KHS
  • K2SO3
  • KHSO3
  • K2SO4
  • KHSO4
  • KHSO5
  • K2S2O3
  • K2S2O5
  • K2S2O7
  • K2S2O8
  • K2Se
  • K2SeO3
  • K2SeO4
  • K2Te
  • K2TeO3
  • K2TeO4
  • K2Po
pnictogens
  • K3N
  • KNH2
  • KN3
  • KNO2
  • KNO3
  • K3P
  • KH2PO3
  • K3PO4
  • K2HPO4
  • KH2PO4
  • KPF6
  • KAsO2
  • K3AsO4
  • K2HAsO4
  • KH2AsO4
B, C group
  • B4K2O7
  • K2CO3
  • KHCO3
  • K2SiO3
  • K2SiF6
  • K2Al2O4
  • K2Al2B2O7
trans metals
  • K2PtCl4
  • K2Pt(CN)4
  • K2TiF6
  • K2PtCl6
  • K2ReCl6
  • K2ZrF6
  • K4Fe(CN)6
  • K3Fe(CN)6
  • K3Fe(C2O4)3
  • K2FeO4
  • K2MnO4
  • KMnO4
  • K3CrO4
  • K2CrO4
  • K3CrO8
  • KCrO3Cl
  • K2Cr2O7
  • K2Cr3O10
  • K2Cr4O13
  • K4Mo2Cl8
organic
  • KHCO2
  • KCH3CO2
  • KCF3CO2
  • K2C2O4
  • KHC2O4
  • KC12H23O2
  • KC18H35O2
  • C3H2K2O4
  • C4H6KO4
  • C5H7KO4