Praseodymium monoselenide

Praseodymium monoselenide
Identifiers
CAS Number
  • 12038-08-3 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 95747165
ECHA InfoCard 100.031.689 Edit this at Wikidata
EC Number
  • 234-872-0
CompTox Dashboard (EPA)
  • DTXSID5065198 Edit this at Wikidata
InChI
  • InChI=1S/Pr.Se
    Key: FAEQPLMETHVSSH-UHFFFAOYSA-N
  • [Pr].[Se]
Properties
Chemical formula
PrSe
Molar mass 219.87
Density 6.9 g/cm3
Melting point 2,100 °C (3,810 °F; 2,370 K)
Related compounds
Other anions
PrS
PrTe
Other cations
CeSe
NdSe
Related compounds
Pr2Se3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Praseodymium monoselenide is a compound with the chemical formula PrSe. It forms crystals.

Preparation

Praseodymium monoselenide can be prepared by directly reacting praseodymium and selenium at 2100 °C:[1]

Pr + Se → PrSe

The temperature at which selenium and praseodymium start to react when they come into contact is 620 K.[2]

Properties

Praseodymium monoselenide forms cubic crystals, space group Fm3m, unit cell parameters a = 0.5741 nm, Z = 4, and a structure similar to that of sodium chloride.[3][4]

The compound melts congruently[clarification needed] at 2100 °C.[4]

References

  1. ^ Sergeeva, K. P. (2015-07-28). "The territorial structures in the settlement pattern and urbanization". Izvestiya Rossiiskoi Akademii Nauk. Seriya Geograficheskaya. (2): 122. doi:10.15356/0373-2444-2015-2-122. ISSN 0373-2444.
  2. ^ Andreev, O. V.; Kharitontsev, V. B.; Elyshev, A. V. (2013-08-01). "Compositions of phases in the interaction of rare-earth metals with selenium". Russian Journal of Inorganic Chemistry. 58 (8): 910–914. doi:10.1134/S0036023613080020. ISSN 1531-8613.
  3. ^ Predel, B., "Se-Tm (Selenium-Thulium)", Pu-Re – Zn-Zr, Berlin/Heidelberg: Springer-Verlag, pp. 1–2, doi:10.1007/10551312_2721, ISBN 3-540-61742-6, retrieved 2024-01-22
  4. ^ a b Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,2. Moskva: Mašinostroenie. 2001. ISBN 978-5-217-02932-7.
  • v
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Pr(II)
  • PrI2
  • PrSe
  • PrP5
Pr(III)
  • Pr(NO3)3
  • Pr2(SO4)3
  • Pr2(SeO4)3
  • PrF3
  • PrCl3
  • PrBr3
  • PrI3
  • PrN
  • PrP
  • PrAs
  • PrSb
  • PrBi
  • PrOI
  • Pr(CH3COO)3
  • Pr(OH)3
  • Pr2O3
  • Pr2S3
  • Pr(ClO4)3
  • Pr(BrO3)3
  • Pr(IO3)3
  • Pr2(MoO4)3
  • PrPO4
  • Pr(C5H7O2)3
  • PrAsO4
  • PrScO3
  • C6O12Pr2
Organopraseodymium(III) compounds
  • Pr2(CO3)3
  • Pr2(C2O4)3
  • Pr(III,IV)
    • Pr6O11
    Pr(IV)
    • PrF4
    • PrO2
    Pr(V)
    • PrNO
    • v
    • t
    • e
    Salts and covalent derivatives of the selenide ion
    H2Se
    H2Se2
    He
    Li2Se Be SexByOz CSe2
    OCSe
    (CH3)2Se
    (NH4)2Se O F Ne
    Na2Se MgSe Al2Se3 Si PxSey
    -P
    +S Cl Ar
    K2Se CaSe Sc2Se3 TiSe2 V CrSe
    Cr2Se3
    MnSe
    MnSe2
    FeSe CoSe NiSe CuSe ZnSe GaSe
    Ga2Se3
    -Ga
    GeSe
    GeSe2
    -Ge
    As2Se3
    As4Se3
    Se2−
    n
    Br Kr
    Rb2Se SrSe Y2Se3 Zr NbSe2
    NbSe3
    MoSe2 Tc Ru Rh Pd Ag2Se CdSe In2Se3 SnSe
    SnSe2
    -Sn
    Sb2Se3 Te +I Xe
    Cs2Se BaSe * LuSe
    Lu2Se3
    Hf TaSe2 WSe2
    WSe3
    ReSe2 Os Ir PtSe2 Au HgSe Tl2Se PbSe Bi2Se3 Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg CnSe Nh Fl Mc Lv Ts Og
     
    * LaSe
    La2Se3
    CeSe
    Ce2Se3
    PrSe
    Pr2Se3
    NdSe
    Nd2Se3
    Pm SmSe
    Sm2Se3
    EuSe
    Eu2Se3
    GdSe
    Gd2Se3
    TbSe
    Tb2Se3
    DySe
    Dy2Se3
    HoSe
    Ho2Se3
    ErSe
    Er2Se3
    TmSe
    Tm2Se3
    YbSe
    Yb2Se3
    ** Ac ThSe2 Pa USe2 Np PuSe Am Cm Bk Cf Es Fm Md No