Selenium tetraazide

Selenium tetraazide
Names
IUPAC name
Selenium(IV) tetraazide
Other names
Selenium tetraazide
Identifiers
CAS Number
  • 1003019-88-2 checkY
3D model (JSmol)
  • Interactive image
PubChem CID
  • 139263047
InChI
  • InChI=1S/N12Se/c1-5-9-13(10-6-2,11-7-3)12-8-4
    Key: RAHBAOGFMBUQBX-UHFFFAOYSA-N
  • [N-]=[N+]=N[Se](N=[N+]=[N-])(N=[N+]=[N-])N=[N+]=[N-]
Properties
Chemical formula
Se(N3)4
Molar mass 247.05 g/mol
Appearance Yellow solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Selenium tetraazide is an inorganic chemical compound with the formula Se(N3)4. It is a highly sensitive explosive, and has been prepared directly from selenium tetrafluoride and trimethylsilyl azide.

Properties

Selenium tetraazide is a yellow solid which precipitates frequently due to its low solubility. The compound is very susceptible to combustion even at low temperatures, and was only found to stably exist at -50 degrees Celsius.[1]

References

  1. ^ Klapötke, Thomas M.; Krumm, Burkhard; Scherr, Matthias; Haiges, Ralf; Christe, Karl O. (8 November 2007). "The Binary Selenium(IV) Azides Se(N3)4, [Se(N3)5], and [Se(N3)6]2−". Angewandte Chemie. 46 (45): 8686–8690. doi:10.1002/anie.200702758. PMID 17935101. Retrieved 3 November 2023.
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Selenium compounds
Se(−II)
  • Se2−
  • H2Se
  • Al2Se3
  • Sb2Se3
  • As2Se3
  • Bi2Se3
  • CdSe
  • CaSe
  • CSe2
  • OCSe
  • CrSe
  • CoSe
  • CuSe
  • (CH3)2Se
  • GaSe
  • Ga2Se3
  • GeSe
  • In2Se3
  • FeSe
  • PbSe
  • MgSe
  • MnSe
  • MnSe2
  • HgSe
  • MoSe2
  • NiSe
  • NbSe2
  • NbSe3
  • PxSey
  • PuSe
  • ReSe2
  • Sm2Se3
  • Ag2Se
  • Na2Se
  • SnSe
  • TiSe2
  • WSe2
  • USe2
  • ZnSe
Se(0,I)
  • Se3S5
Se(I)
  • Se2S6
  • Se2Cl2
  • C3H7NO2Se
Se(II)
  • SeBr2
  • SeCl2
  • SeS2
Se(IV)
  • SeO2−3
  • SeBr4
  • SeCl4
  • SeF4
  • SeO2
  • SeS2
  • SeOBr2
  • SeOCl2
  • H2SeO3
Se(VI)
  • SeO2−4
  • SeF6
  • SeO3
  • SeO2F2
  • H2SeO4
Se(IV,VI)
  • SeO2−4 + SeO2−3
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Salts and covalent derivatives of the azide ion
HN3 He
LiN3 Be(N3)2 B(N3)3 CH3N3
C(N3)4
CO(N3)2
NH4N3
N3NO
N(N3)3
H2N–N3
O FN3 Ne
NaN3 Mg(N3)2 Al(N3)3 Si(N3)4 P SO2(N3)2 ClN3 Ar
KN3 Ca(N3)2 Sc(N3)3 Ti(N3)4 VO(N3)3 Cr(N3)3
CrO2(N3)2
Mn(N3)2 Fe(N3)2
Fe(N3)3
Co(N3)2
Co(N3)3
Ni(N3)2 CuN3
Cu(N3)2
Zn(N3)2 Ga(N3)3 Ge As(N3)5 Se(N3)4 BrN3 Kr
RbN3 Sr(N3)2 Y(N3)3 Zr(N3)4 Nb Mo Tc Ru(N3)63− Rh(N3)63− Pd(N3)2 AgN3 Cd(N3)2 In Sn Sb(N3)5 Te(N3)4 IN3 Xe(N3)2
CsN3 Ba(N3)2 * Lu(N3)3 Hf Ta W Re Os Ir(N3)63− Pt(N3)62− Au(N3)4 Hg2(N3)2
Hg(N3)2
TlN3 Pb(N3)2 Bi(N3)3 Po At Rn
Fr Ra(N3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(N3)3 Ce(N3)3
Ce(N3)4
Pr Nd Pm Sm(N3)3 Eu(N3)2
Eu(N3)3
Gd(N3)3 Tb Dy(N3)3 Ho(N3)3 Er Tm Yb(N3)3
** Ac(N3)3 Th(N3)4 Pa UO2(N3)2 Np Pu Am Cm Bk Cf Es Fm Md No
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