Silver chlorate

Silver chlorate
Silver(I) chlorate
Names
IUPAC name
Silver(I) chlorate
Systematic IUPAC name
Silver(I) chlorate(V)
Other names
Argentous chlorate
Identifiers
CAS Number
  • 7783-92-8 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 7991255 checkY
ECHA InfoCard 100.029.122 Edit this at Wikidata
EC Number
  • 232-034-9
PubChem CID
  • 9815505
UNII
  • O4T3J400JU checkY
CompTox Dashboard (EPA)
  • DTXSID50228454 Edit this at Wikidata
InChI
  • InChI=1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: SDLBJIZEEMKQKY-UHFFFAOYSA-M checkY
  • InChI=1/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: SDLBJIZEEMKQKY-REWHXWOFAI
  • [Ag+].[O-]Cl(=O)=O
Properties
Chemical formula
 AgClO3
Molar mass 191.319 g/mol
Appearance white crystals
Density 4.443 g/cm3, solid
Melting point 230 °C (446 °F; 503 K)
Boiling point 250 °C (482 °F; 523 K) (decomposes)
Solubility in water
 slightly soluble
Solubility soluble in water and ethanol alcohol
Structure
Crystal structure
 tetragonal
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
2
0
1
OX
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Silver chlorate (AgClO3) forms white, tetragonal crystals.[1][2] Like all chlorates, it is water-soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers.

The substance exhibits blasting properties, therefore it is sometimes used as a primary explosive.

Silver(I) means silver is in its normal +1 oxidation state.

Production

Silver chlorate is produced by the reaction of silver nitrate with sodium chlorate to produce both silver chlorate and sodium nitrate.

Alternatively, it may be produced by the transmission of chlorine through a suspension of silver oxide.

See also

References

  1. ^ Náray-Szabó, St. v.; Pócza, J. (January 1942). "Die Struktur des Silberchlorats AgClO3". Zeitschrift für Kristallographie - Crystalline Materials (in German). 104 (1): 28–38. doi:10.1524/zkri.1942.104.1.28. S2CID 102075872.
  2. ^ Deshpande, Vilas; Suryanarayana, S V; Frantz, C (December 1982). "Tetragonal to cubic phase transition in silver chlorate". Bulletin of Materials Science. 4 (5): 563–568. doi:10.1007/BF02824963.
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Silver(0,I)
  • Ag2F
Silver(I)
  • AgBF4
  • AgBr
  • AgBrO3
  • AgCN
  • AgCNO
  • AgCl
  • AgClO
  • AgClO2
  • AgClO3
  • AgClO4
  • AgF
  • AgI
  • AgIO3
  • AgMnO4
  • AgNO2
  • AgNO3
  • AgN3
  • Ag3N
  • AgReO4
  • AgOCN
  • AgSCN
  • AgCF3SO3
  • AgPF6
  • Ag2CO3
  • Ag2C2
  • Ag2C2O4
  • Ag2CrO4
  • Ag2Cr2O7
  • Ag2MoO4
  • Ag2O
  • Ag2S
  • Ag2SO3
  • Ag2S2O3
  • Ag2SO4
  • AgHSO4
  • Ag2Se
  • Ag2SeO3
  • Ag2Te
  • Ag3AsO4
  • Ag3PO4
  • KAg(CN)2
  • RbAg4I5
  • Ag(NH3)2OH
  • Ag2N2O2
  • Ag2WO4
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18    H
    36    AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11    H
    23    COO
    • Silver(II)
    • AgF2
    • [Ag(C5H5N)4]S2O8
    Silver(III)
    • Ag2O3
    • AgF3
    • Ag2S3
    Silver(I,III)
    • Ag4O4
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    Salts and covalent derivatives of the chlorate ion
    HClO3 He
    LiClO3 Be B C NH4ClO3 O F Ne
    NaClO3 Mg(ClO3)2 Al(ClO3)3 Si P S Cl Ar
    KClO3 Ca(ClO3)2 Sc Ti V Cr Mn(ClO3)2 Fe(ClO3)3 Co(ClO3)2 Ni(ClO3)2 Cu(ClO3)2 Zn(ClO3)2 Ga(ClO3)3 Ge As Se Br Kr
    RbClO3 Sr(ClO3)2 Y(ClO3)3 Zr Nb Mo Tc Ru Rh Pd AgClO3 Cd(ClO3)2 In Sn Sb Te I Xe
    CsClO3 Ba(ClO3)2 * Lu Hf Ta W Re Os Ir Pt AuClO3 Hg(ClO3)2 Tl Pb(ClO3)2 Bi Po At Rn
    Fr Ra(ClO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(ClO3)2 Ce Pr(ClO3)2 Nd Pm Sm Eu Gd Tb Dy Ho Er(ClO3)2 Tm Yb
    ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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