Silver oxalate

Silver oxalate
Names
IUPAC name
Silver(I) ethanedioate
Other names
Silver Ethanedioate, Silver Salt
Argentous oxalate
Silver(I) oxalate
Identifiers
CAS Number
  • 533-51-7 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 56153 checkY
ECHA InfoCard 100.007.791 Edit this at Wikidata
EC Number
  • 208-568-3
PubChem CID
  • 62364
RTECS number
  • RO2900000
UNII
  • NE0L2ZGZ13 checkY
CompTox Dashboard (EPA)
  • DTXSID90201448 Edit this at Wikidata
InChI
  • InChI=1S/C2H2O4.2Ag/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2 checkY
    Key: XNGYKPINNDWGGF-UHFFFAOYSA-L checkY
  • InChI=1/C2H2O4.2Ag/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2
    Key: XNGYKPINNDWGGF-NUQVWONBAW
  • [Ag+].[Ag+].[O-]C(=O)C([O-])=O
Properties
Chemical formula
Ag
2
C
2
O
4
Molar mass 303.755 g/mol
Appearance white powder
Density 5.03 g/cm3
Melting point 961.9 °C (1,763.4 °F; 1,235.0 K) (decomposes)
Boiling point 2,212 °C (4,014 °F; 2,485 K) at 1013.25 hPa
Solubility in water
3.270*10−3 g/100mL
Solubility product (Ksp)
5.4×10−12[1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Harmful if swallowed
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Silver oxalate (Ag
2
C
2
O
4
)
is commonly employed in experimental petrology to add carbon dioxide (CO
2
) to experiments as it will break down to silver (Ag) and carbon dioxide under geologic conditions.[2] It is also a precursor to the production of silver nanoparticles. It is explosive upon heating around 140 degrees Celsius, shock or friction. [3]

Production

Silver oxalate is produced by the reaction between silver nitrate and oxalic acid.

See also

References

  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. ^ Silver Oxalate at American Elements
  3. ^ Silver Oxalate MSDS sheet Archived 2013-12-12 at the Wayback Machine at mpbio

External links

  • Synthesizing Silver Oxalate
  • Chemical Entity Data Page
  • v
  • t
  • e
Silver(0,I)
  • Ag2F
Silver(I)
  • AgBF4
  • AgBr
  • AgBrO3
  • AgCN
  • AgCNO
  • AgCl
  • AgClO
  • AgClO2
  • AgClO3
  • AgClO4
  • AgF
  • AgI
  • AgIO3
  • AgMnO4
  • AgNO2
  • AgNO3
  • AgN3
  • Ag3N
  • AgReO4
  • AgOCN
  • AgSCN
  • AgCF3SO3
  • AgPF6
  • Ag2CO3
  • Ag2C2
  • Ag2C2O4
  • Ag2CrO4
  • Ag2Cr2O7
  • Ag2MoO4
  • Ag2O
  • Ag2S
  • Ag2SO3
  • Ag2S2O3
  • Ag2SO4
  • AgHSO4
  • Ag2Se
  • Ag2SeO3
  • Ag2Te
  • Ag3AsO4
  • Ag3PO4
  • KAg(CN)2
  • RbAg4I5
  • Ag(NH3)2OH
  • Ag2N2O2
  • Ag2WO4
Organosilver(I) compounds
  • AgC2H3O2
  • AgC22H43O2
  • CH3CH(OH)COOAg
  • C
    18
    H
    36
    AgO
    2
  • AgC4H3N2NSO2C6H4NH2
  • AgC
    11
    H
    23
    COO
  • Silver(II)
    • AgF2
    • [Ag(C5H5N)4]S2O8
    Silver(III)
    • Ag2O3
    • AgF3
    • Ag2S3
    Silver(I,III)
    • Ag4O4
    • v
    • t
    • e
    Salts of the oxalate ion
    (H2C2O4) He
    Li2C2O4 BeC2O4 +BO3 +CO3 (NH4)2C2O4
    +NO3
    O F Ne
    Na2C2O4
    NaHC2O4
    MgC2O4 Al Si +PO4
    +PO3
    +SO4 +Cl Ar
    K2C2O4
    KHC2O4
    CaC2O4 Sc Ti V CrC2O4 MnC2O4 FeC2O4
    Fe2(C2O4)3
    +Fe
    humboldtine
    +NH4 +Na +K +K
    CoC2O4 -Ni CuC2O4 Katsarosite Ga2(C2O4)3 Ge As Se Br Kr
    Rb2C2O4 SrC2O4 Y2(C2O4)3 Zr Nb(HC2O4)5 Mo Tc Ru Rh Pd Ag2C2O4 CdC2O4 In2(C2O4)3 SnC2O4 Sb Te I Xe
    Cs2C2O4 BaC2O4 * Lu2(C2O4)3 Hf Ta W Re Os Ir -Pt Au Hg Tl PbC2O4 Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La2(C2O4)3 Ce2(C2O4)3 Pr2(C2O4)3 Nd2(C2O4)3 Pm2(C2O4)3 Sm2(C2O4)3 Eu2(C2O4)3 Gd2(C2O4)3 Tb2(C2O4)3 Dy2(C2O4)3 Ho2(C2O4)3 Er2(C2O4)3 Tm2(C2O4)3 Yb2(C2O4)3
    ** Ac2(C2O4)3 Th(C2O4)2 Pa UO2C2O4 Np(C2O4)2 Pu(C2O4)2 Am Cm2(C2O4)3 Bk2(C2O4)3 Cf2(C2O4)3 Es2(C2O4)3 Fm Md No