Sodium deuteroxide

Sodium deuteroxide[1]
Names
IUPAC name
Sodium deuteroxide
Other names
  • Deuterated sodium hydroxide
  • Sodium hydroxide-d
Identifiers
CAS Number
  • 14014-06-3
3D model (JSmol)
  • Interactive image
ChemSpider
  • 9193979
EC Number
  • 237-825-2
PubChem CID
  • 23676750
CompTox Dashboard (EPA)
  • DTXSID80930715 Edit this at Wikidata
InChI
  • InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hD
    Key: HEMHJVSKTPXQMS-DYCDLGHISA-M
  • [Na+].[O-][2H]
Properties
Chemical formula
NaOD
Molar mass 41.003 g/mol
Appearance White solid
Solubility in water
Soluble
Hazards
GHS labelling:
Pictograms
GHS05: Corrosive
Danger
Hazard statements
H290, H314
Precautionary statements
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Related compounds
Related compounds
Sodium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform,[2] and reaction with N-nitrosodimethylamine gives the deuterated analog of that compound.[3][full citation needed] Sodium deuteroxide is an ionic compound, consisting of sodium cations Na+ and deuteroxide anions OD.

References

  1. ^ "Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.
  2. ^ Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.
  3. ^ National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.
  • v
  • t
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Inorganic
Halides
Chalcogenides
  • NaO3
  • NaO2
  • Na2O
  • Na2O2
  • NaOH
  • NaOD
  • Na2S
  • NaSH
  • Na2Se
  • NaSeH
  • Na2Te
  • NaHTe
  • Na2Po
Pnictogenides
  • Na3N
  • NaN3
  • NaNH2
  • Na3P
  • Na3As
Oxyhalides
  • NaClO
  • NaClO2
  • NaClO3
  • NaClO4
  • NaBrO
  • NaBrO2
  • NaBrO3
  • NaBrO4
  • NaIO3
  • NaIO4
Oxychalcogenides
  • Na2SO3
  • Na2SO4
  • NaHSO3
  • NaHSO4
  • Na2S2O3
  • Na2S2O4
  • Na2S2O5
  • Na2S2O6
  • Na2S2O7
  • Na2S2O8
  • Na2SeO3
  • Na2SeO4
  • NaHSeO3
  • Na2TeO3
Oxypnictogenides
  • NaNO2
  • NaNO3
  • Na2N2O2
  • NaH2PO4
  • NaPO2H2
  • Na2HPO3
  • Na2PO3F
  • Na3PS2O2
  • Na3PO4
  • Na5P3O10
  • Na4P2O7
  • Na2H2P2O7
  • Na3AsO3
  • Na3AsO4
  • Na2HAsO4
  • NaH2AsO4
  • NaSbO3
Others
  • NaAlH4
  • NaAlO2
  • Na3AlF6
  • NaAl(SO4)2
  • NaAuCl4
  • Na2TiF6
  • NaBH4
  • NaBH3(CN)
  • NaBO2
  • Na2B4O7
  • Na2B2O9
  • Na2B8O13
  • NaBiO3
  • NaCN
  • NaCNO
  • NaCoO2
  • NaH
  • NaHCO3
  • Na4XeO6
  • NaHXeO4
  • NaMnO4
  • NaOCN
  • NaReO4
  • NaSCN
  • NaTcO3
  • NaTcO4
  • NaVO3
  • Na2CO3
  • Na2C2O4
  • Na2C3S5
  • Na2CrO4
  • Na2Cr2O7
  • Na2Cr3O10
  • Na2GeO3
  • Na2He
  • Na2[Fe(CO)4]
  • Na2MnO4
  • Na2MoO4
  • Na3IrCl6
  • Na2PtCl6
  • Na2O(UO3)2
  • Na2S4O6
  • Na2SiO3
  • Na2TiO3
  • Na2U2O7
  • Na2WO4
  • Na2Zn(OH)4
  • Na3VO4
  • Na6V10O28
  • Na4Fe(CN)6
  • Na3Fe(CN)6
  • Na3Fe(C2O4)3
  • Na4SiO4
  • Na2SiF6
  • Na3[Co(NO2)6]
  • NaNSi6
  • Na2PdCl4
Organic
  • CH3ONa
  • C2H5ONa
  • HCOONa
  • C2H5COONa
  • C3H7COONa
  • Na2C4H4O6
  • C4H5NaO6
  • NaCH3COO
  • NaC6H5CO2
  • NaC6H4(OH)CO2
  • NaC12H23O2
  • NaC10H8
  • Na2[Fe[CN5]NO]
  • C6H16AlNaO4
  • NaC6H7O6
  • C5H8NO4Na
  • C6H5Na
  • C4H9Na
  • NaC5H5
  • C15H31COONa
  • C17H33COONa
  • C18H35O2Na
  • C164H256O68S2Na2