Sulfate fluoride

Class of chemical compounds

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1][2]

Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.

List

Minerals

name formula ratio system space group unit cell Å volume density optical references
Chukhrovite-(Ca) Ca4.5Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.749 Z=8 4698.6 2.23 isotropic n = 1.432 [3]
Chukhrovite-(Ce) Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [4]
Chukhrovite-(Y) Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [5]
Chukhrovite-(Nd) Ca3(Nd,Y)Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.759 Z=8 4,707.0 2.42 isotropic nα = 1.443 [6]
Meniaylovite Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O 1:13 Isometric Fd3 a = 16.722 Z=8 4,675.89 Isotropic n = 1.43
Pseudograndreefite Pb6(SO4)F10 1:10 Orthorhombic F2 2 2 a = 8.51 b = 19.57 c = 8.49 Z=4 1,413.93 Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.873

2V: measured: 30° , calculated: 40°

Max birefringence: δ = 0.009

[7]
Creedite Ca3SO4Al2F8(OH)2 · 2H2O 1:8 Monoclinic B2/b a = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=4 1,194.02 2.713 Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485

Max birefringence: δ = 0.024

[8]
Thermessaite K2AlF3(SO4) 1:3 Orthorhombic Pbcn a = 10.81 b = 8.336 c = 6.822 614.75 2.77
Grandreefite Pb2(SO4)F2 1:2 monoclinic A2/a a = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4 523.15 7.15 Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.897

2V: Measured: 23°

Max Birefringence: δ = 0.025

[9]
Arangasite Al2F(PO4)(SO4) · 9H2O 1:1 monoclinic P2/a a = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2 725.7 2.01 Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)

Max birefringence: δ = 0.008

[10][11]
Khademite Al(SO4)F · 5H2O 1:1 orthorhombic a = 11.17 b = 13.05 c = 10.88 1,585.96 1.925 Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.487

2V: measured: 68° calculated: 84°

Max birefringence δ = 0.047

colourless

[12]
Kogarkoite Na3(SO4)F 1:1 Monoclinic ?P21 a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=12 1,366.58 2.676 Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442

Max Birefringence: δ = 0.003

[13]
kononovite NaMg(SO4)F 1:1 monoclinic C2/c a = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4 367.4 2.91 biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°

Max birefringence: δ = 0.008

[14]
Lannonite Mg2Ca4Al4(SO4)8F8 · 24H2O 8:8 Tetragonal I4/m a = 6.860 c = 28.053 1,320.16 2.22 Uniaxial (+) nω = 1.460 nε = 1.478

Max Birefringence:δ = 0.018

[15]
Sulphohalite Na6(SO4)2FCl 2:1 Isometric Fm3m Isotropic [16]
Uklonskovite NaMgSO4F•2H2O 1:1 monoclinic a = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23° 273.34 Biaxial (+) nα = 1.476 nγ = 1.500

Max Birefringence δ = 0.024

[17]
Vlodavetsite AlCa2(SO4)2F2Cl · 4H2O 2:2 Tetragonal I4/m a = 6.870, c = 13.342 Z=2 629.70 Uniaxial (+) nω = 1.509 nε = 1.526

Max birefringence: δ = 0.017

[18]
Schairerite Na21(SO4)7ClF6 7:6 trigonal 3_2/m a = 12.17 c = 19.29 2,474.25 2.67 Uniaxial (+) nω = 1.440 nε = 1.445

Max birefringence: δ = 0.005

[19]
Galeite Na15(SO4)5F4Cl 5:4 Trigonal a = 12.17 c = 13.94 1,788.03 Uniaxial (+) nω = 1.447 nε = 1.449

Max Birefringence: δ = 0.002

[20]
Fluorellestadite Ca10(SiO4)3(SO4)3F2 3:2 hexagonal a = 9.53 c = 6.91 543.49 3.03 Uniaxial (-) nω = 1.655 nε = 1.650

Max birefringence:δ = 0.005

[21]
Straßmannite Al(UO2)(SO4)2F·16H2O 2:1 monoclinic C2/c a = 11.0187 b = 8.3284 c = 26.673 β = 97.426° 2427.2 2.20 pale yellowish green

Biaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2)

2V: measured: 70° calculated: 70.2°

Max birefringence: δ = 0.012

[22]
Svyazhinite (Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O 2:1 triclinic a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08° 510.29 Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444

2V: calculated: 56°

Max birefringence: δ = 0.021

[23]
Wilcoxite MgAl(SO4)2F · 17H2O 2:1 triclinic P1 a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487 579.6 1.58 Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438

2V: measured: 48° , calculated: 44°

Max birefringence: δ = 0.014

[24]
Krasheninnikovite KNa2CaMg(SO4)3F 3:1 hexagonal P63/mcm a = 16.6682 c = 6.9007 Z = 6 1660.36 2.68 Uniaxial (-) nω = 1.500 nε = 1.492

Max birefringence: δ = 0.008

[25]
Shuvalovite K2(Ca2Na)(SO4)3F 3:1 orthorhombic Pnma a = 13.2383 b = 10.3023 c = 8.9909 Z = 4 1226.22 2.64 biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20 [26]
Thermessaite-(NH4) (NH4)2AlSO4F3 1:3 orthorhombic Pbcn a = 11.3005 b = 8.6125 c = 6.8501 Z = 4 666.69 [27]

Artificial

name formula MW ratio system space group unit cell volume density optical CAS references
LiMgFSO4 1:1 triclinic P1 a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2 [28]
NaMgSO4F 1:1 monoclinic C2/c Z=4 109.802 2.84 [29]
Na2AlSO4F3 1:1 monoclinic P2/c a=6.3562 b=6.2899 c=7.1146 β=115.687° Z=2 256.33 2.928 [30]
Li4NH4Al(SO4)2F4 2:4 monoclinic C2/c a=13.6561 b=4.9761 c=13.9919 β=92.135° Z=4 950.2 2.383 [30]
Na4TiF4(SO4)2 2:4 [31]
β-K3[SO4]F 1:1 tetragonal I4/mcm a= 7.2961 c= 10.854 [32]
α-K3[SO4]F 1:1 cubic Pm3m a≈5.43 ≥585 °C [32]
KMgSO4F 178.47 1:1 orthorhombic Pna21 a=12.973 b=6.4585 c=10.635 Z=8 891.1 2.661 colourless [33][34]
Li6K3Al(SO4)4F4 4:4 triclinic P1 a=5.0304 b=9.5690 c=9.7078 α=70.968° β=75.531° γ=75.183° Z=1 420.08 2.554 [30]
sodium calcium sulfapatite Na6Ca4(SO4)6F2 6:2
K3Ca2(SO4)3F 3:1 orthorhombic Pn21a a=13.467 b=10.521 c=9.167 Z=4 1299.9 [35]
[N2C10H12] TiF4SO4 378.16? 1:4 triclinic P1 a=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2               683.6 1.837 colourless [31]
[N2C10H12]TiF2(SO4)2 436.22? 2:2 triclinic P1 a=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1               371.11 1.952 colourless [31]
Rb2TiF2(SO4)2 · 2H2O 1:1 [36]
Cs2TiF2(SO4)2 · 3H2O 1:1 [36]
[N2C6H16]V(SO4)2F 378.27 2:1 monoclinic P21/c a=10.262 b =17.761 c=7.0518 β=93.93 Z=4                  1282.3 1.959 green [31]
Na2VF3SO4 1:3 [31]
Na3CrF2(SO4)2 2:2 [31]
LiMnSO4F 1:1 monoclinic a=13.2406 b=6.4082 c=10.0229 β=120.499 732.76 [37]
[N2C6H16]2+Mn2F2(SO4)2 2:2 [31]
Li2MnF3(SO4) 1:3 pink-brown [38]
(NH4)2MnF3(SO4) 1:3 pink-brown [38]
Na2MnF3(SO4) 1:3 pink-brown [38]
Dipotassium trifluorosulfato manganate(III) K2MnF3(SO4) 1:3 pink-brown [38]
FeFSO4 170.91 1:1 monoclinic C2/c a = 7.3037 b = 7.0753 c = 7.3117 β = 119.758° 328.017 3.461 [39]
K2FeF3SO4 1:3 [31]
Li3FeF2(SO4)2·H2O 2:2 [31]
[N2C6H16]Fe(SO4)2F 383.18 2:1 monoclinic P21/c a=10.2220 b=17.6599 c=7.0437 β=93.894 Z=4 1268.59 2.006 brown [31]
LiFeFSO4 177.85 1:1 triclinic P1 a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865° 182.44 3.237 grass green [39]
sodium ferrous sulfate fluoride NaFeFSO4 193.91 1:1 monoclinic P21/c a = 6.6739 b = 8.6989 c = 7.1869 β = 113.525° 382.567 3.366 [39]
sodium ferrous sulfate fluoride dihydrate NaFeFSO4·2H2O 1:1 monoclinic P21/m a=5.75959 b=7.38273 c=7.25047 β=113.3225 283.109 white [40]
trisodium ferric disulfate difluoride Na3Fe(SO4)2F2 2:2 orthorhombic Pnca a = 6.6419 b = 8.8115 c = 14.0023 [41]
NaCoFSO4 1:1 monoclinic C2/c a=6.6687 b=8.6251 c=7.1444 β=114.323 374.46 [42]
NaCoFSO4·2H2O 1:1 monoclinic P21/m a=5.73364 b=7.31498 c=7.18640 β=113.5028 276.40 pink [40]
NH4CoFSO4·2H2O 1:1 [43]
KCoFSO4·2H2O 1:1 [43]
NaNiFSO4·2H2O 1:1 monoclinic P21/m a=5.70118 b=7.27603 c=7.15634 β=113.8883 271.429 green [40]
LiZnSO4F 1:1 orthorhombic Pnma 7.40357 b=6.32995 c=7.42016 347.740 [44]
KZnSO4F 219.53 1:1 orthorhombic Pna21 a=13.0602 b=6.4913 c=10.7106 Z=8 908.02 3.212 transparent <190 nm [34]
K2Zn3(SO4)(HSO4)2F4 1:4 orthorhombic Cmc21 a=17.725 b=7.6650 c=9.7505 Z=4 1324.7 3.212 colourless [45]
Li4RbAl(SO4)2F4 2:4 monoclinic C2/c a=13.6503 b=4.984 c=14.0081 β=91.509° Z=4 948.82 2.858 [46]
Y(SO4)F 203.97 1:1 orthorhombic Pnma a=8.3128, b=6.9255, c=6.3905 Z=4 367.90 3.682 [47]
YSO4F·H2O 1:1 monoclinic P21/n a=4.9707 b=7.306 c=11.493 β =96.95° birefringence 0.0357 at 546 nm [48]
Y2Cu(OH)3(SO4)2F·H2O 521.52 2:1 monoclinic P21/n a=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4 997.8 3.472 blue [47]
KYSO4F2 1:2 monoclinic P21/m a=6.4402 b=5.7784 c=6.992 β=113.684° Z=2 238.30 3.652 band gap 7.79 eV; birefringence 0.015 @ 546.1 nm [49]
RbYSO4F2 1:2 monoclinic P21/m a=6.5347 b=5.8212 c=7.1383 β=114.332° Z=2 247.42 4.140 band gap 7.82 eV; birefringence 0.02 @ 546.1 nm [49]
Zr2O2F2SO4 · 6H2O 1:2 [50]
α-K3ZrF5SO4 · H2O 1:5 [36]
K2ZrF4SO4 1:4 [36]
K2ZrF2(SO4)2 · 2.5H2O 2:2 [36]
K3Zr2F9SO4 · 2H2O 1:9 [36]
(NH4)3Zr2F9SO4 · 2H2O 1:9 [36]
(NH4)2ZrF4SO4 1:4 [36]
(NH4)2ZrF2(SO4)2 · 2.5H2O 2:2 [36]
Rb2ZrF4SO4 1:4 [36]
Rb2ZrF2(SO4)2 · 3H2O 2:2 [36]
Rb3Zr2F9SO4 ·2H2O 1:9 [36]
RbZr2O2F(SO4)2 · 5H2O 2:1 [36]
Cs2ZrF4SO4 1:4 [36]
Cs2ZrF2(SO4)2 · 2H2O 2:2 [36]
Cs8Zr4F2(SO4)11 · 16H2O 11:2 [36]
CsZr2O2F(SO4)2 · 6H2O 2:1 [36]
Zr2O2F2SO4 · 5H2O 1:2 [36]
triindium trifluoride sulfate ditellurite hydrate In3(SO4)(TeO3)2F3(H2O) 866.74 1:3 orthorhombic P212121 a=8.3115 b=9.4341 c=14.8068 1161.0 4.959 band gap 4.10 eV; white [51]
4,4'-bipyridine distannous difluoride disulfate (C10H10N2)0.5[SnF(SO4)] 2:2 triclinic P1 a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2 398.3 2.608 colourless [52]
diantimony dipotassium hexafluoride sulfate K2SO4·(SbF3)2 531.76 1:6 monoclinic P21/c a=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4 973.40 3.629 colourless [53]
diantimony dirubidium hexafluoride sulfate Rb2SO4·(SbF3)2 624.50 1:6 monoclinic P21 a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2 516.1 4.018 colourless [53]
tetraantimony hexarubidium dodecafluoride trisulfate Rb6Sb4F12(SO4)3 1515.989 3:12 trigonal P3 a=16.9490 c=7.5405 Z=2 1875.94 4.026 white 53168-89-1 [54][55]
hexaammonium dodecafluorotrisulfatotetraantimonate(III) [NH4]6Sb4F12(SO4)3 3:12 trigonal P3 a=17.07 c=7.515 Z=3 1896 2.92 [56]
hexarubidium dodecafluorotrisulfatotetraantimonate(III) Rb6Sb4F12(SO4)3 3:12 [56]
Li4CsAl(SO4)2F4 2:4 monoclinic C2/c a=13.574 b=5.0427 c=14.258 β=91.961° Z=4 975.7 3.103 [46]
tetraantimony hexacaesium dodecafluoride trisulfate Cs6Sb4F12(SO4)3 1800.601 3:12 triclinic P1 a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=4 1394.3 4.289 white 53200-54-7 [54][57]
antimony caesium difluoride sulfate CsSbF2SO4 388.72 1:2 orthorhombic Pna21 a=9.9759 b=11.6616 c=5.2968 515.20 4.19 clear, non-linear SH [58]
LiLa2F3(SO4)2 2:3 monoclinic I2/a a = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4 [59]
CeF2(SO4) 1:2 orthorhombic Pca21 a=8.3668 b=6.3600 c=8.3862 birefringence 0.361@ 546 nm; SHG 8×KDP [60]
NdFSO4·H2O 277.32 1:1 monoclinic P21/n a = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4 425.37 4.330 pink [61]
NaPr2F3(SO4)2 2:3 monoclinic I2/a a = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4 light green [62]
LiEr2F3(SO4)2 2:3 orthorhombic Pbcn a = 14.791, b = 6.336, c = 8.137 [59]
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride [C4H16N3]6[Sm4F2(SO4)14] 2621.43 14:2 triclinic P1 a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=1 1903.9 2.286 colourless [61]
TbFSO4·H2O 292.00 1:1 monoclinic P21/n a = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4 426.9 4.543 colourless [61]
gadolinium fluoride sulfate GdF[SO4] 1:1 orthorhombic Pnma a=8.436 b=7.0176 c=6.4338 Z=4 [63]
γ-K2HfF2(SO4)2 · 2H2O 2:2 [36]
K2HfF2(SO4)2 · 2.5H2O 2:2 [36]
Na6Pb4(SO4)6F2 6:2 [64]
ThSO4F2.H2O 1:2 monoclinic P21n a = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4 502.98 colourless [65]
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrate K2UF2O2(SO4)·H2O 1:2 monoclinic P21/c a = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4 867.1 3.83 greenish yellow [66][67]
(NH4)2[UO2F2(SO4)] triclinic P1 a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2 greenish yellow [67]
(NH4)6[(UO2)2F4(SO4)3] triclinic P1 a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1 greenish yellow [67]
Cs2[(UO2)2F4(SO4)] greenish yellow [67]
(NH4)[UO2F(SO4)] triclinic P1 a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=1 1.92 greenish yellow [67]
RbUO2SO4F orthorhombic Pca21 a=25.353 b=6.735 c=11.496 Z=12 [68][69]
[N2C6H16][UO2F2(SO4)] 520.29 1:2 triclinic P1 a=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2 629.62 2.744 yellow [70]
[N2C6H16][UO2F(SO4)]2 884.37 2:2 orthorhombic Pmmn a=6.9503 b=17.2147 c=7.0867 Z=2 847.90 3.464 yellow [70]
[N2C3H12][UO2F(SO4)]2·H2O 862.32 2:2 orthorhombic Pnma a=13.5775 b=14.6180 c=8.1168 Z=4 1610.99 3.555 yellow [70]
[N2C5H14][UO2F(H2O)(SO4)]2 907.38 2:2 monoclinic P121/n1 a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=4 1935.0 3.115 yellow [70]
[N2C6H18]2[UO2F(SO4)]4·H2O 1792.80 4:4 triclinic P1 a=10.8832 b=10.9386 c=16.5325 α=75.6604 β=73.6101 γ=89.7726 Z=2 1824.73 3.263 yellow [70]
[N2C3H12][UO2F(SO4)]2·H2O 864.34 2:2 monoclinic P121/n1 a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2 791.54 3.626 yellow [70]
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfate U4+3F4(SO4)6·2NH4·H3N-NH3 1436.6 6:4 monoclinic C2/c a=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=4 2432.69 4.392 green [71]

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  • v
  • t
  • e
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
LiF BeF2 BF
BF3
B2F4
+BO3 		CF4
CxFy
+CO3 		NF3
FN3
N2F2
NF
N2F4
NF2
?NF5 		OF2
O2F2
OF
O3F2
O4F2
?OF4 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4 		ClF
ClF3
ClF5 		?ArF2
?ArF4
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
?CrF6 		MnF2
MnF3
MnF4
?MnF5 		FeF2
FeF3
FeF4 		CoF2
CoF3
CoF4 		NiF2
NiF3
NiF4 		CuF
CuF2
?CuF3 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6
+SeO3 		BrF
BrF3
BrF5 		KrF2
?KrF4
?KrF6
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF4
MoF5
MoF6 		TcF4
TcF
5
TcF6 		RuF3
RuF
4
RuF5
RuF6 		RhF3
RhF4
RhF5
RhF6 		PdF2
Pd[PdF6]
PdF4
?PdF6 		Ag2F
AgF
AgF2
AgF3 		CdF2 InF
InF3 		SnF2
SnF4 		SbF3
SbF5 		TeF4
?Te2F10
TeF6
+TeO3 		IF
IF3
IF5
IF7
+IO3 		XeF2
XeF4
XeF6
?XeF8
CsF BaF2   LuF3 HfF4 TaF5 WF4
WF5
WF6 		ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6
?OsF
7
?OsF
8 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
Pt[PtF6]
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
?AuF6
AuF5•F2 		Hg2F2
HgF2
?HgF4 		TlF
TlF3 		PbF2
PbF4 		BiF3
BiF5 		?PoF2
PoF4
PoF6 		AtF
?AtF3
?AtF5 		RnF2
?RnF
4
?RnF
6
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3
PrF4 		NdF2
NdF3
NdF4 		PmF3 SmF2
SmF3 		EuF2
EuF3 		GdF3 TbF3
TbF4 		DyF2
DyF3
DyF4 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3
AcF3 ThF3
ThF4 		PaF4
PaF5 		UF3
UF4
UF5
UF6 		NpF3
NpF4
NpF5
NpF6 		PuF3
PuF4
PuF5
PuF6 		AmF2
AmF3
AmF4
? AmF6 		CmF3
CmF4
 ?CmF6 		BkF3
BkF
4 		CfF3
 ?CfF4 		EsF3
EsF4
?EsF6 		Fm Md No
  • v
  • t
  • e
Compounds containing the sulfate group (SO2−4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9
-BO3
+BO3 		esters
ROSO−3
(RO)2SO2
+CO3
+C2O4 		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3 		HOSO4 +F Ne
Na2SO4
NaHSO4 		MgSO4 Al2(SO4)3
Al2SO4(OAc)4 		Si +PO4 SO2−4
HSO3HSO4
(HSO4)2
+SO3 		+Cl Ar
K2SO4
KHSO4 		CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4 		CrSO4
Cr2(SO4)3 		MnSO4 FeSO4
Fe2(SO4)3 		CoSO4
Co2(SO4)3 		NiSO4
Ni2(SO4)3 		CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4 		ZnSO4 Ga2(SO4)3 Ge As +SeO3 Br Kr
RbHSO4
Rb2SO4 		SrSO4 Y2(SO4)3 Zr(SO4)2 Nb2O2(SO4)3 MoO(SO4)2
MoO2(SO4) 		Tc Ru(SO4)2 Rh2(SO4)3 PdSO4 Ag2SO4
AgSO4 		CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2 		Sb2(SO4)3 Te +IO3 Xe
Cs2SO4
CsHSO4 		BaSO4 * Lu2(SO4)3 Hf Ta WO(SO4)2 Re2O5(SO4)2 OsSO4
Os2(SO4)3
Os(SO4)2 		IrSO4
Ir2(SO4)3 		Pt2(SO4)54– AuSO4
Au2(SO4)3 		Hg2SO4
HgSO4 		Tl2SO4
Tl2(SO4)3 		PbSO4
Pb(SO4)2 		Bi2(SO4)3 PoSO4
Po(SO4)2 		At Rn
Fr RaSO4 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SO4)3 Ce2(SO4)3
Ce(SO4)2 		Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 EuSO4
Eu2(SO4)3 		Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3
** Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4 		Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf2(SO4)3 Es Fm Md No