Tungsten nitride

Chemical compound of tungsten and nitrogen

Tungsten nitride (W2N, WN, WN2) is an inorganic compound, a nitride of tungsten.[1] It is a hard, solid, brown-colored ceramic material that is electrically conductive and decomposes in water.

It is used in microelectronics as a contact material, for conductive layers, and barrier layers between silicon and other metals, e.g. tungsten or copper. It is less commonly used than titanium nitride or tungsten films.

Tungsten nitride forms together with tungsten dioxide, tungsten trioxide, and tungsten pentoxide when an incandescent light bulb breaks while the filament is heated.

Tungsten silicide is another material with similar use.

References

  1. ^ Liu, Chengxiang; Wang, Chao; Meng, Xiangwei; Li, Xingyun; Qing, Qing; Wang, Xianfen; Xue, Ruiying; Yu, Qiang; Yang, Jialei; Wang, Kuikui; Zhao, Xiaoju; Chen, Wei; Qiao, Zhen-An; Zhao, Xiu Song (2020-11-01). "Tungsten nitride nanoparticles anchored on porous borocarbonitride as high-rate anode for lithium ion batteries". Chemical Engineering Journal. 399: 125705. doi:10.1016/j.cej.2020.125705. ISSN 1385-8947. S2CID 224904157.
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Tungsten compounds
Tungsten(0)
  • W(CO)6
  • W(PMe3)6
Tungsten(II)
  • WSi2
  • WCl2
  • WI2
  • W(OH)2
  • W2(hpp)4
Tungsten(III)
  • W2O3
  • WCl3
  • WI3
  • W2(OtBu)6
Tungsten(IV)
  • WC
  • WO2
  • WS2
  • WSe2
  • WTe2
  • WF4
  • WCl4
  • WBr4
  • WI4
Tungsten(V)
  • W2O5
  • WBr5
  • W2Cl10
Tungsten(VI)
  • WO2Cl2
  • WBr6
  • WCl6
  • WF6
  • WN2
  • WO3
  • WS3
  • WAs2
  • WOBr4
  • WOCl4
  • WOF4
  • H2WO4
Organotungsten(VI) compounds
  • W(CH3)6
Polytungstate salts
  • H3PW12O40
  • (NH4)10(H2W12O42)
  • Na6[H2W12O40]
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Salts and covalent derivatives of the nitride ion
NH3
N2H4
+H
HN2−
H2N
He(N2)11
Li3N
LiN3
Be3N2
Be(N3)2
BN
-B
C2N2
β-C3N4
g-C3N4
CxNy
N2 NxOy
+O
N3F
N2F2
N2F4
NF3
+F
Ne
Na3N
NaN3
Mg3N2
Mg(N3)2
AlN Si3N4
-Si
PN
P3N5
-P
SxNy
SN
S2N2
S4N4
SN2H2
NCl3
ClN3
+Cl
Ar
K3N
KN3
Ca3N2
Ca(N3)2
ScN TiN
Ti3N4
VN CrN
Cr2N
MnxNy FexNy Co3N Ni3N Cu3N Zn3N2 GaN Ge3N4
-Ge
AsN
+As
Se4N4 Br3N
BrN3
+Br
Kr
RbN3 Sr3N2
Sr(N3)2
YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N Cd3N2 InN Sn SbN Te4N4? I3N
IN3
+I
Xe
CsN3 Ba3N2
Ba(N3)2
* LuN HfN
Hf3N4
TaN WN RexNy Os Ir Pt Au Hg3N2 Tl3N (PbNH) BiN Po At Rn
Fr Ra3N2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaN CeN PrN NdN PmN SmN EuN GdN TbN DyN HoN ErN TmN YbN
** Ac Th PaN UxNy NpN PuN AmN CmN BkN Cf Es Fm Md No
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