Uranium monosulfide

Uranium monosulfide
Identifiers
CAS Number
  • 12039-11-1
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/S.U
    Key: BFEBVEVTVKJYGD-UHFFFAOYSA-N
  • [U].[S]
Properties
Chemical formula
US
Molar mass 270.095 g/mol
Melting point 2460 °C [1]
Structure[1]
Crystal structure
NaCl type (cubic)
Space group
Fm3m (No. 225)
Lattice constant
a = 548.66 pm
Formula units (Z)
4
Related compounds
Other anions
Uranium carbide
Uranium monophosphide
Related compounds
Uranium disulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Uranium monosulfide (US) is an inorganic chemical compound of uranium and sulfur.[2]

Magnetically, the compound is paramagnetic at room temperature, with a Curie Temperature of 180 K.[3] It has the largest known magnetocrystalline anisotropy of any cubic system.[4]

References

  1. ^ a b NAKAI, Eiichiro; KANNO, Masayoshi; MUKAIBO, Takashi (1969). "Oxidation Behavior of Uranium Monosulfide". Journal of Nuclear Science and Technology. 6 (3). Informa UK Limited: 138–142. Bibcode:1969JNST....6..138N. doi:10.1080/18811248.1969.9732854. ISSN 0022-3131.
  2. ^ "Uranium monosulfide". webbook.nist.gov. Retrieved 2022-11-23.
  3. ^ Westrum, Edgar F.; Walters, Robert R.; Flotow, Howard E.; Osborne, Darrell W. (1968). "Uranium Monosulfide. The Ferromagnetic Transition. The Heat Capacity and Thermodynamic Properties from 1.5 to 350 K". The Journal of Chemical Physics. 48 (1). AIP Publishing: 155–161. Bibcode:1968JChPh..48..155W. doi:10.1063/1.1667893. hdl:2027.42/70623. ISSN 0021-9606.
  4. ^ Poudel, Narayan; Jeffries, Jason; Gofryk, Krzysztof (2021-07-14). "Magnetic anisotropy in uranium monosulfide probed by magnetic torque measurements". Physical Review B. 104 (1). American Physical Society (APS): 014417. arXiv:2106.12464. Bibcode:2021PhRvB.104a4417P. doi:10.1103/physrevb.104.014417. ISSN 2469-9950. S2CID 235606157.
  • v
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  • v
  • t
  • e
U(II)
  • UB2
  • US
U(III)
  • UF3
  • UCl3
  • UBr3
  • UI3
  • UP
  • U(OH)3
  • UH3
  • UN
Organouranium(III) compounds
  • U(C5H5)3
  • U(IV)
    • U(BH4)4
    • UC
    • UCl4
    • UF4
    • UBr4
    • UI4
    • UO2
    • UH4
    • USi2
    • US2
    • USe2
    • UTe2
    • U(SO4)2
    Organouranium(IV) compounds
  • U(C8H8)2
  • U(C5H5)4
  • U(C5H5)3Cl
  • U(IV,V)
    • U2N3
    U(IV,VI)
    • U3O8
    U(V)
    • UCl5
    • UF5
    • UBr5
    • UI5
    • U2O5
    U(VI)
    • (NH4)2U2O7
    • Na2U2O7
    • UCl6
    • UF6
    • U(PO4)2
    • UO3
    • UO4
    • UO2(CH3COO)2
    • UO2(CHO2)2
    • UO2CO3
    • UO2CO3·2(NH4)2CO3
    • UO2Cl2
    • UO2F2
    • UO2(NO3)2
    • UO2(OH)2
    • (UO2)2(OH)4
    • UO2(SO4)2
    • ZnUO2(CH3COO)4
    • UN2
    • H2UO4
    • Na4UO2(CO3)3
    U(XII)
    • UO6 (hypothetical)
    • v
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    • e
    Sulfides (S2−)
    H2S He
    Li2S BeS B2S3
    +BO3
    CS2
    COS
    (NH4)SH O F Ne
    Na2S MgS Al2S3 SiS
    SiS2
    -Si
    PxSy
    -P
    -S2−
    2
    Cl Ar
    K2S CaS ScS
    Sc2S3
    TiS
    TiS2
    Ti2S3
    TiS3
    VS
    VS2
    V2S3
    CrS
    Cr2S3
    MnS
    MnS2
    FeS
    Fe3S4
    CoS NiS Cu2S
    CuS
    ZnS GaS
    Ga2S3
    GeS
    GeS2
    -Ge
    As2S3
    As4S3
    -As
    SeS2
    +Se
    Br Kr
    Rb2S SrS Y2S3 ZrS2 NbS2 MoS2
    MoS3
    Tc Ru Rh2S3 PdS Ag2S CdS In2S3 SnS
    SnS2
    -Sn
    Sb2S3
    Sb2S5
    -Sb
    TeS2 I Xe
    Cs2S BaS * LuS
    Lu2S3
    HfS2 TaS2 WS2
    WS3
    ReS2
    Re2S7
    OsS
    4
    Ir2S3
    IrS2
    PtS
    PtS2
    Au2S
    Au2S3
    HgS Tl2S PbS
    PbS2
    Bi2S3 PoS At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * LaS
    La2S3
    CeS
    Ce2S3
    PrS
    Pr2S3
    NdS
    Nd2S3
    Pm2S3 SmS
    Sm2S3
    EuS
    Eu2S3
    GdS
    Gd2S3
    TbS
    Tb2S3
    DyS
    Dy2S3
    HoS
    Ho2S3
    ErS
    Er2S3
    TmS
    Tm2S3
    YbS
    Yb2S3
    ** Ac2S3 ThS2 Pa US
    US2
    Np Pu Am Cm Bk Cf Es Fm Md No