Phosphide bromide

Class of chemical compounds

Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br−) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.

List

formula system space group unit cell Å volume density comment ref
Ca2PBr cubic I43d a=5.96 Z=2 red brown [1]
Ca2PBr hexagonal R3m a=4.23 c=20.9 Z=3 [1]
Cu12P20Br10 triclinic P a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2 1786.1 [2]
Cu13P15Br12 [3]
Cu6PS5Br cubic P43m a=9.732 Z=4 921.8 4.701 red [4]
(CuBr)2P8Se3 orthorhombic Pbcm a=8.761 b=11.957 c=13.858 Z=4 1451.8 [5]
Sr2PBr cubic I43d a=9.31 Z=2 brown violet [1]
Sr2PBr hexagonal R3m a=4.44 c=22.0 Z=3 dark reddish brown [1]
Sr2P7Br cubic P213 a=9.789 Z=4 938.0 3.342 red band gap 2.1 eV [6]
Y2PBr2 rhombohedral a=3.9807 c=29.250 [7]
Ag6PS5Br cubic P43m a=10.3765 Z=4 1117.26 5.460 red [4]
Cd5P2Br4 orthorhombic Pna21 a=12.189, b=7.7080, c=13.664 [8]
Sn24P19.3Br8 [9]
Sn17Zn7P22Br8 cubic Pm3n a=10.7449 [10]
Sn24−xInxP19.2+0.2x x<16 cubic Pm3n [11]
Si30+xP16–xTe8–xBrx x = 1–6.4 cubic Pm3n a=9.9720 - 10.0405 [12]
Ba2PBr hexagonal R3m a=4.67 c=23.3 Z=3 [1]
Ba2P7Br monoclinic P21/m a=6.294 b=6.835 c=11.850 β=95.819 Z=2 507.2 3.742 orange [13]
La2PBr2 trigonal P3m1 a=4.311 c=11.000 Z=1 177.04 5.28 [7]
La3Zn4P6.6Br0.8 orthorhombic Cmcm a=4.099 b=14.229 c=20.388 Z=4 1189.0 5.290 black [14]
Eu2PBr R3m a = 4.385, c = 21.90, Z = 3 [15]
W4(PBr)Br10 monoclinic C12/m1 a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 1715.16 dark green [16]
Hg2P3Br orthorhombic Pbcn a = 8.014, b = 8.902, c = 7.823, Z = 4 [17]
Hg7P4Br6 monoclinic P21/c a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 879.3 7.582 brown [18]
(Hg2P)2HgBr4 monoclinic P21 a=7.776 b=12.226 c=7.930 β=121.34 Z=2 643.9 7.141 discovered in 1907; bright yellow; air with light sensitive [19]
[Hg7P4Br3](SnBr3) cubic P213 a=12.490 Z=4 [20]

References

  1. ^ a b c d e Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01). "Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium". Zeitschrift für Naturforschung B. 30 (5–6): 378–384. doi:10.1515/znb-1975-5-616. ISSN 1865-7117. S2CID 94967271.
  2. ^ Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.). "Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer". Zeitschrift für Kristallographie - Crystalline Materials. 212 (2): 103–109. Bibcode:1997ZK....212..103F. doi:10.1524/zkri.1997.212.2.103. ISSN 2194-4946.
  3. ^ Freudenthaler, E (November 1997). "Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors". Solid State Ionics. 101–103: 1053–1059. doi:10.1016/S0167-2738(97)00169-0.
  4. ^ a b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.
  5. ^ Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004). "(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs". Journal of Molecular Structure. 706 (1–3): 89–94. Bibcode:2004JMoSt.706...89N. doi:10.1016/j.molstruc.2004.01.037.
  6. ^ Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140.
  7. ^ a b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
  8. ^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd5P2Br4 - the first cadmium analogue of salts of Millon's base" [Cd5P2Br4 - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.
  9. ^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.
  10. ^ Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005). "Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures". Solid State Sciences. 7 (8): 957–968. doi:10.1016/j.solidstatesciences.2005.04.002.
  11. ^ Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.
  12. ^ Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05). "Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties". Inorganic Chemistry. 51 (21): 11396–11405. doi:10.1021/ic3010097. ISSN 0020-1669. PMID 23072375.
  13. ^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.
  14. ^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
  15. ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
  16. ^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.
  17. ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
  18. ^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.
  19. ^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.
  20. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
  • v
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Salts and covalent derivatives of the bromide ion
HBr He
LiBr BeBr2 BBr3
+BO3 		CBr4
+C 		NBr3
BrN3
NH4Br
NOBr
+N 		Br2O
BrO2
Br2O3
Br2O5 		BrF
BrF3
BrF5 		Ne
NaBr MgBr2 AlBr
AlBr3 		SiBr4 PBr3
PBr5
PBr7
+P 		S2Br2
SBr2 		BrCl Ar
KBr CaBr2
 ScBr3 TiBr2
TiBr3
TiBr4 		VBr2
VBr3 		CrBr2
CrBr3 		MnBr2 FeBr2
FeBr3 		CoBr2 NiBr2
NiBr42− 		CuBr
CuBr2 		ZnBr2 GaBr3 GeBr2
GeBr4 		AsBr3
+As
+AsO3 		SeBr2
SeBr4 		Br2 Kr
RbBr SrBr2 YBr3 ZrBr3
ZrBr4 		NbBr5 MoBr2
MoBr3
MoBr4 		TcBr4 RuBr3 RhBr3 PdBr2 AgBr CdBr2 InBr
InBr3 		SnBr2
SnBr4 		SbBr3
+Sb
-Sb 		Te2Br
TeBr4
+Te 		IBr
IBr3 		XeBr2
CsBr BaBr2 * LuBr3 HfBr4 TaBr5 WBr5
WBr6 		ReBr3 OsBr3
OsBr4 		IrBr3
IrBr
4 		PtBr2
PtBr4 		AuBr
AuBr3 		Hg2Br2
HgBr2 		TlBr PbBr2 BiBr3 PoBr2
PoBr4 		AtBr Rn
FrBr RaBr2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaBr3 CeBr3 PrBr3 NdBr2
NdBr3 		PmBr3 SmBr2
SmBr3 		EuBr2
EuBr3 		GdBr3 TbBr3 DyBr3 HoBr3 ErBr3 TmBr2
TmBr3 		YbBr2
YbBr3
** AcBr3 ThBr4 PaBr4
PaBr5 		UBr4
UBr5 		NpBr3
NpBr4 		PuBr3 AmBr2
AmBr3 		CmBr3 BkBr3 CfBr3 EsBr2
EsBr3 		Fm Md No
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Binary phosphides
PH3 He
Li3P Be BP CP
+C 		N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP 		P S +Cl Ar
K3P Ca3P2
CaP 		ScP TiP V CrP
Cr3P 		Mn FeP CoP
Co2P
Co3P2 		NixPy Cu3P Zn3P2
ZnP2 		GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2 		NbP Mo3P
MoP
MoP2 		Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* LaP CeP PrP
PrP5 		NdP Pm SmP
SmP5 		EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also